Volume 56, Issue 6 pp. e247-e248

(Aceto­nitrile-N)(o-benzo­quinone di­imine-N,N′)­chloro-trans-bis­(tri­phenyl­phosphine-P)­ruthenium(II) hexa­fluoro­phosphate 0.25-hydrate

First published: 30 June 2004
Diego Venegas-Yazigi, e-mail: [email protected]

Abstract

The Ru atom in the title compound, [RuCl(CH3CN){P(C6H5)3}2{C6H4(NH)2}]PF6·0.25H2O, has a six-coordinate octahedral geometry, with a trans arrangement of the tri­phenyl­phosphine groups. The asymmetric unit contains two complex mol­ecules and a partially occupied water site. Principal dimensions include Ru—N 1.958 (4)–2.044 (5), Ru—P 2.3897 (16)–2.4092 (15), and Ru—Cl 2.4280 (15) and 2.4295 (16) Å

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