Cover Picture
Free Access
Front Cover: Synthesis and Characterization of a Calcium-Pyrazolonato Complex. Observation of In-Situ Desolvation During Micro-Electron Diffraction (Z. Anorg. Allg. Chem. 5/2023)
First published: 28 February 2023
Graphical Abstract
The cover picture shows the microcrystalline particle size of the Ca-pyrazolonato complex with its diffraction pattern under micro-ED conditions. The pattern could be identified to show a Ca-pyrazolonato complex with an axial water ligand. The indicated shift along the b-axis of the diffraction pattern which was attributed to the loss of a water ligand from the Ca-pyrazolonato complex under the applied conditions of the microED measurement resulted in a second structure solution. This underlines that these conditions can result in the desolvation of highly electrophilic and oxophilic metal complexes (Ca) (DOI: 10.1002/zaac.202200294).
