Supramolecular Architectures of Four New Transition Metal Complexes with 3-[4-(Carboxymethoxy)phenyl]propanoic Acid and N-[4-(Carboxymethoxy)phenyl]iminodiacetic Acid
Corresponding Author
Prof. Dr. Chong-Bo Liu
School of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, P. R. China
School of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, P. R. ChinaSearch for more papers by this authorHui-Liang Wen
State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047, P. R. China
Search for more papers by this authorYun-Nan Gong
School of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, P. R. China
Search for more papers by this authorXiao-Ming Liu
School of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, P. R. China
Search for more papers by this authorSheng-Shui Tan
State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047, P. R. China
Search for more papers by this authorCorresponding Author
Prof. Dr. Chong-Bo Liu
School of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, P. R. China
School of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, P. R. ChinaSearch for more papers by this authorHui-Liang Wen
State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047, P. R. China
Search for more papers by this authorYun-Nan Gong
School of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, P. R. China
Search for more papers by this authorXiao-Ming Liu
School of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, P. R. China
Search for more papers by this authorSheng-Shui Tan
State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047, P. R. China
Search for more papers by this authorAbstract
Four new transition metal complexes: [Cu(Hcppa)2(H2O)2] (1), [Co2(cppa)2(H2O)10] (2), [Co3(cpia)2(H2O)8]·2H2O (3) and [Ni3(cpia)2(H2O)12]·6H2O (4) {H2cppa = 3-(4-(carboxymethoxy)phenyl]propanoic acid; H3cpia = N-[4-(carboxymethoxy)phenyl]iminodiacetic acid} were synthesized and characterized. Complexes 1 and 2 show mononuclear structures, complexes 3 and 4 exhibit dinuclear structures. All complexes extend to 3D supramolecular networks through hydrogen bonds, of which complexes 3 and 4 display microporous structures. In complexes 2–4 the water clusters are trapped by the cooperative association of coordinate interactions as well as hydrogen bonds, forming different 1D metal-water chain structures. Thermal stabilities of complexes 1–4 were discussed.
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