Zur Reaktivität von alkylthioverbrückten 44-CVE-triangularen Platinclustern: Umsetzungen mit bidentaten Phosphanliganden†
Christian Albrecht
Halle/Saale, Institut für Chemie der Universität
Search for more papers by this authorChristoph Wagner
Halle/Saale, Institut für Chemie der Universität
Search for more papers by this authorCorresponding Author
Dirk Steinborn Prof. Dr.
Halle/Saale, Institut für Chemie der Universität
Martin-Luther-Universität Halle-Wittenberg, Institut für Chemie Anorganische Chemie, Kurt-Mothes-Straße 2, D-06120 Halle / GermanySearch for more papers by this authorChristian Albrecht
Halle/Saale, Institut für Chemie der Universität
Search for more papers by this authorChristoph Wagner
Halle/Saale, Institut für Chemie der Universität
Search for more papers by this authorCorresponding Author
Dirk Steinborn Prof. Dr.
Halle/Saale, Institut für Chemie der Universität
Martin-Luther-Universität Halle-Wittenberg, Institut für Chemie Anorganische Chemie, Kurt-Mothes-Straße 2, D-06120 Halle / GermanySearch for more papers by this authorProfessor Heinrich Nöth zum 80. Geburtstag gewidmet
Abstract
On the Reactivity of Alkylthio Bridged 44 CVE Triangular Platinum Clusters: Reactions with Bidentate Phosphine Ligands
The 44 cve (cluster valence electrons) triangular platinum clusters [{Pt(PR3)}3(μ-SMe)3]Cl (PR3 = PPh3, 2a; P(4-FC6H4)3, 2b; P(n-Bu)3, 2c) were found to react with PPh2CH2PPh2 (dppm) in a degradation reaction yielding dinuclear platinum(I) complexes [{Pt(PR3)}2(μ-SMe)(μ-dppm)]Cl (PR3 = PPh3, 3a; P(4-FC6H4)3, 3b; P(n-Bu)3; 3e) and the platinum(II) complex [Pt(SMe)2(dppm)] (4), whereas the addition of PPh2CH2CH2PPh2 (dppe) to cluster 2a afforded a mixture of degradation products, among others the complexes [Pt(dppe)2] and [Pt(dppe)2]Cl2. On the other hand, the treatment of cluster 2a with PPh2CH2CH2CH2PPh2 (dppp) ended up in the formation of the cationic complex [{Pt(dppp)}2(μ-SMe)2]Cl2 (5). Furthermore, the terminal PPh3 ligands in complex 3a proved to be subject to substitution by the stronger donating monodentate phosphine ligands PMePh2 and PMe2Ph yielding the analogous complexes [{Pt(PR3)}2(μ-SMe)(μ-dppm)]Cl (PR3 = PMePh2, 3c; PMe2Ph, 3d). NMR investigations on complexes 3 showed an inverse correlation of Tolmans electronic parameter ν with the coupling constants 1J(Pt,P) and 1J(Pt,Pt). All compounds were fully characterized by means of NMR and IR spectroscopy. X-ray diffraction analyses were performed for the complexes [{Pt{P(4-FC6H4)3}}2(μ-SMe)(μ-dppm)]Cl (3b), [Pt(SMe)2(dppm)] (4), and [{Pt(dppp)}2(μ-SMe)2]Cl2 (5).
REFERENCES
- 1a L. H. Gade, Angew. Chem., 1993, 105, 25. Angew. Chem. Int. Ed. Engl., 1993, 32, 21.
- 1b A. Simon, Angew. Chem., 1988, 100, 163. Angew. Chem. Int. Ed. Engl., 1988, 27, 159.
- 1c M. D. Morse, Chem. Rev., 1986, 86, 1049.
- 1d M. H. Chrisholm, I. P. Rothwell, Progr. Inorg. Chem., 1982, 29, 1.
- 1e J. D. Corbett, Acc. Chem. Res., 1981, 14, 239.
- 1f A. Simon, Angew. Chem., 1981, 93, 23. Angew. Chem. Int. Ed. Engl., 1981, 20, 1.
- 1g F. A. Cotton, Acc. Chem. Res., 1978, 6, 225.
- 1h R. B. King, Progr. Inorg. Chem., 1972, 15, 287.
- 1i H. Schäfer, H. G. v. Schnering, Angew. Chem., 1964, 76, 833.
- 2a P. J. Dyson, Coord. Chem. Rev., 2004, 248, 2443.
- 2b
P. Schwerdtfeger,
Angew. Chem.,
2003,
115,
1936.
10.1002/ange.200201610 Google ScholarAngew. Chem. Int. Ed., 2003, 42, 1892.
- 2c H. Paul, S. Bhaduri, G. K. Lahiri, Organometallics, 2003, 22, 3019.
- 2d L. Guczi, A. Beck, A. Horváth, D. Horváth, Top. Catal., 2002, 19, 157.
- 2e G. Schmid, Chem. Rev., 1992, 92, 1709.
- 2f K. Wieghardt, Angew. Chem., 1989, 101, 1179. Angew. Chem. Int. Ed. Engl., 1989, 28, 1153.
- 2g E. L. Muetterties, M. J. Krause, Angew. Chem., 1983, 95, 135. Angew. Chem. Int. Ed. Engl., 1983, 22, 135.
- 2h E. L. Muetterties, Chem. Soc. Rev., 1982, 11, 283.
- 2i R. H. Holm, Chem. Soc. Rev., 1981, 10, 455.
- 2j M. Moskovits, Acc. Chem. Res., 1979, 12, 229.
- 3a F. A. Cotton, G. Wilkinson, C. A. Murillo, M. Bochmann, Advanced Inorganic Chemistry, Wiley, New York 1999.
- 3b
A. F. Holleman,
N. Wiberg, Lehrbuch der Anorganischen Chemie, de Gruyter, Berlin 2007.
10.1515/9783110177701 Google Scholar
- 4a C. Albrecht, S. Schwieger, C. Bruhn, C. Wagner, R. Kluge, H. Schmidt, D. Steinborn, J. Am. Chem. Soc., 2007, 129, 4551.
- 4bC. Albrecht, Dissertation, Martin-Luther-Universität Halle-Wittenberg, Halle 2007.
- 5a R. A. Burrow, D. H. Farrar, J. J. Irwin, Inorg. Chim. Acta, 1991, 181, 65.
- 5b N. Hadj-Bagheri, J. Browning, K. Dehghan, K. R. Dixon, N. J. Meanwell, R. Vefghi, J. Organomet. Chem., 1990, 369, C 47.
- 5c D. M. P. Mingos, I. D. Williams, M. J. Watson, J. Chem. Soc., Dalton Trans., 1988, 1509.
- 6a N. Hadj-Bagheri, R. J. Puddephatt, Inorg. Chim. Acta, 1993, 213, 29.
- 6b A. M. Bradford, M. C. Jennings, R. J. Puddephatt, Organometallics, 1989, 8, 2367.
- 6c N. Hadj-Bagheri, R. J. Puddephatt, Inorg. Chem., 1989, 28, 2384.
- 6d M. C. Jennings, N. C. Payne, R. J. Puddephatt, Inorg. Chem., 1987, 26, 3776.
- 6e M. F. Hallam, M. A. Luke, D. M. P. Mingos, I. D. Williams, J. Organomet. Chem., 1987, 325, 271.
- 7 M. F. Hallam, N. D. Howells, D. M. P. Mingos, R. W. M. Wardle, J. Chem. Soc., Dalton Trans., 1985, 845.
- 8a H. K. Yip, C. M. Che, S. M. Peng, J. Chem. Soc., Dalton Trans., 1993, 179.
- 8b X. Hong, H. K. Yip, K. K. Cheung, C. M. Che, J. Chem. Soc., Dalton Trans., 1993, 815.
- 8c M. N. I. Khan, C. King, J. C. Wang, S. Wang, J. P. FacklerJr., Inorg. Chem., 1989, 28, 4656.
- 8d R. J. Blau, J. H. Espenson, S. Kim, R. A. Jacobson, Inorg. Chem., 1986, 25, 757.
- 8e L. Manojlovic-Muir, K. W. Muir, T. Solomun, Acta Crystallogr., 1979, B 35, 1237.
- 8f L. Manojlovic-Muir, K. W. Muir, T. Solomun, J. Organomet. Chem., 1979, 179, 479.
- 8g M. P. Brown, J. R. Fisher, L. Manojlovic-Muir, K. W. Muir, R. J. Puddephatt, M. A. Thomson, K. R. Seddon, J. Chem. Soc., Chem. Commun., 1979, 931.
- 9a H. Liu, A. L. Tan, K. F. Mok, T. S. A. Hor, J. Chem. Soc., Dalton Trans., 1996, 4023.
- 9b A. C. Skapski, P. G. H. Troughton, J. Chem. Soc., A, 1969, 2772.
- 10 H. Schmidbaur, G. Reber, A. Schier, F. E. Wagner, G. Müller, Inorg. Chim. Acta, 1988, 147, 143.
- 11 S. I. Al-Resayes, P. B. Hitchcock, J. F. Nixon, J. Organomet. Chem., 1984, 267, C 13.
- 12Cambridge Structural Database (CSD), Cambridge University Chemical Laboratory, Cambridge 2006.
- 13a C. T. Hunt, G. B. Matson, A. L. Balch, Inorg. Chem., 1981, 20, 2270.
- 13b S. Berger, S. Braun, H.-O. Kalinowski, NMR-Spektroskopie von Nichtmetallen, Bd. 3, Thieme, Stuttgart 1993.
- 14a
P. S. Pregosin,
Annual Reports on NMR Spectroscopy, Academic Press, London 1986.
10.1016/S0066-4103(08)60238-0 Google Scholar
- 14b P. S. Pregosin, Coord. Chem. Rev., 1982, 44, 247.
- 15a C. A. Tolman, Chem. Rev., 1977, 77, 313.
- 15b W. Strohmeier, F. J. Müller, Chem. Ber., 1967, 100, 2812.
- 16a
G. Aullón,
G. Ujaque,
A. Lledós,
S. Alvarez,
Chem. Eur. J.,
1999,
5,
1391.
10.1002/(SICI)1521-3765(19990503)5:5<1391::AID-CHEM1391>3.0.CO;2-C CAS Web of Science® Google Scholar
- 16b P. Conzález-Duarte, A. Lledós, R. Mas-Ballesté, Eur. J. Inorg. Chem., 2004, 3585.
- 17a S. H. Chong, A. Tjindrawan, T. S. A. Hor, J. Mol. Catal. A, 2003, 204-205, 267.
- 17b R. Mas-Balleste, M. Capdevila, P. A. Champkin, W. Clegg, R. A. Coxall, A. Lledos, C. Megret, P. Gonzalez-Duarte, Inorg. Chem., 2002, 41, 3218.
- 17c M. Capdevila, Y. Carrasco, W. Clegg, R. A. Coxall, P. Gonzalez-Duarte, A. Lledos, J. Sola, G. Ujaque, Chem. Commun., 1998, 597.
- 18 A. Albinati, G. Carturan, A. Musco, Inorg. Chim. Acta, 1976, 16, L 3.
- 19a C. S. Browning, D. H. Farrar, R. R. Gukathasan, S. A. Morris, Organometallics, 1985, 4, 1750.
- 19b A. Moor, P. S. Pregosin, L. M. Venanzi, Inorg. Chim. Acta, 1982, 61, 135.
- 19c J. Chatt, P. Chini, J. Chem. Soc., A, 1970, 1538.
- 20
H. Günther,
Angew. Chem.,
1972,
19,
907.
10.1002/ange.19720841902 Google ScholarAngew. Chem. Int. Ed. Engl., 1972, 10, 861.
- 21PERCH-NMR-Software, Version 1/2000, University of Kuopio 2000.
- 22G. M. Sheldrick, SHELXS-97, SHELXL-97, Programs for Crystal Structure Determination, Universität Göttingen 1997.
- 23Cambridge Crystallographic Data Centre. Kopien der Daten können unter Angabe der Hinterlegungsnummern CCDC 676593-676595 kostenlos bei folgender Adresse angefordert werden: The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (e-mail: [email protected]).
- 24 L. J. Farrugia, J. Appl. Cryst., 1997, 30, 565.
