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X-Ray Photoelectron Spectroscopy of Palladium Fluorides^†

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Dr. A. Tressaud

Laboratoire De Chimie du Solide du CNRS, Université De Bordeaux-I, 351, Cours De la Libération, 33405 Talence Cedex, France

Laboratoire De Chimie du Solide du CNRS, Université De Bordeaux-I, 351, Cours De la Libération, 33405 Talence Cedex, FranceSearch for more papers by this author

Dr. S. Khairoun,

Dr. S. Khairoun

Laboratoire De Chimie du Solide du CNRS, Université De Bordeaux-I, 351, Cours De la Libération, 33405 Talence Cedex, France

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Dr. H. Touhara,

Dr. H. Touhara

Department of Industrial Chemistry, Faculty of Engineering, Kyoto University, Kyoto 606, Japan

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Prof. Dr. N. Watanabe,

Prof. Dr. N. Watanabe

Department of Industrial Chemistry, Faculty of Engineering, Kyoto University, Kyoto 606, Japan

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Dr. A. Tressaud,

Corresponding Author

Dr. A. Tressaud

Laboratoire De Chimie du Solide du CNRS, Université De Bordeaux-I, 351, Cours De la Libération, 33405 Talence Cedex, France

Laboratoire De Chimie du Solide du CNRS, Université De Bordeaux-I, 351, Cours De la Libération, 33405 Talence Cedex, FranceSearch for more papers by this author

Dr. S. Khairoun,

Dr. S. Khairoun

Laboratoire De Chimie du Solide du CNRS, Université De Bordeaux-I, 351, Cours De la Libération, 33405 Talence Cedex, France

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Dr. H. Touhara,

Dr. H. Touhara

Department of Industrial Chemistry, Faculty of Engineering, Kyoto University, Kyoto 606, Japan

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Prof. Dr. N. Watanabe,

Prof. Dr. N. Watanabe

Department of Industrial Chemistry, Faculty of Engineering, Kyoto University, Kyoto 606, Japan

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First published: September/Oktober 1986

https://doi.org/10.1002/zaac.19865400932

Citations: 118

^†

Dedicated to Professor Paul Hagenmuller on his 65th Birthday

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Abstract

X-ray photoelectron spectra of several Palladium fluorine compounds have been investigated. In all these phases Palladium atoms have a more or less distorted octahedral coordination. Satellite Structures generally occur in Pd 3d_3/2 and Pd 3d_5/2 levels and broad F 1s peaks are observed. Shifts in binding energies can be correlated with Palladium oxidation State and covalency. XPS results clearly confirm the unusual +III oxidation State of Palladium in NaPdF₄, Na₃PdF₆, K₃PdF₆, and K₂NaPdF₆.

Abstract

Röntgen-Photoelektronen-Spektroskopie an Palladiumfluoriden

Die Röntgen-Photoelektronenspektren Von mehreren Palladium-Fluor-Verbindungen wurden untersucht. In allen diesen Phasen haben die Palladiumatome eine mehr oder weniger gestörte oktaedrische Koordination. Setellitenstrukturen zeigen sich im allgemeinen im Pd 3d_3/2 und Pd 3d_5/2 Niveau und breite F 1s-Peaks werden beobachtet. Verschiebungen der Bindungsenergien können mit dem Kovalenzgrad und dem Oxydationszustand des Palladiums in Beziehung gesetzt werden. Die XPS-Ergebnisse bestätigen deutlich den ungewöhnlichen Oxydationszustand 3+ des Palladiums in NaPdF₄, Na₃PdF₆, K₃PdF₆ und K₂NaPdF₆.

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Volume540, Issue9-10

September/Oktober 1986

Pages 291-299

X-Ray Photoelectron Spectroscopy of Palladium Fluorides^†

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X-Ray Photoelectron Spectroscopy of Palladium Fluorides†

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X-Ray Photoelectron Spectroscopy of Palladium Fluorides^†