Twinned Metal–Organic Framework Nanoplates for Hydrocarbon Separation Membranes
Jongbum Kim
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
Search for more papers by this authorMinsu Kim
Department of Chemical and Biomolecular Engineering, Yonsei University, 50, Yonsei-ro, Seodaemun-gu, Seoul, 03722 Republic of Korea
Search for more papers by this authorSeungho Yu
Department of Chemical Engineering, Konkuk University, 120, Neungdong-ro, Gwangjin-gu, Seoul, 05029 Republic of Korea
Search for more papers by this authorJihee Yu
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
Search for more papers by this authorChanjong Yu
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
Search for more papers by this authorTaehwan Kim
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
Search for more papers by this authorNahyeon Lee
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
Search for more papers by this authorYun Ho Ahn
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
Search for more papers by this authorYun Ho Kim
Advanced Materials Division, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Advanced Materials and Chemical Engineering, KRICT School, University of Science and Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Search for more papers by this authorSungmi Yoo
Advanced Materials Division, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Search for more papers by this authorKi Chul Kim
Department of Chemical Engineering, Konkuk University, 120, Neungdong-ro, Gwangjin-gu, Seoul, 05029 Republic of Korea
Search for more papers by this authorCorresponding Author
Dae Woo Kim
Department of Chemical and Biomolecular Engineering, Yonsei University, 50, Yonsei-ro, Seodaemun-gu, Seoul, 03722 Republic of Korea
E-mail: [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Kiwon Eum
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
E-mail: [email protected]; [email protected]
Search for more papers by this authorJongbum Kim
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
Search for more papers by this authorMinsu Kim
Department of Chemical and Biomolecular Engineering, Yonsei University, 50, Yonsei-ro, Seodaemun-gu, Seoul, 03722 Republic of Korea
Search for more papers by this authorSeungho Yu
Department of Chemical Engineering, Konkuk University, 120, Neungdong-ro, Gwangjin-gu, Seoul, 05029 Republic of Korea
Search for more papers by this authorJihee Yu
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
Search for more papers by this authorChanjong Yu
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
Search for more papers by this authorTaehwan Kim
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
Search for more papers by this authorNahyeon Lee
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
Search for more papers by this authorYun Ho Ahn
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
Search for more papers by this authorYun Ho Kim
Advanced Materials Division, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Advanced Materials and Chemical Engineering, KRICT School, University of Science and Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Search for more papers by this authorSungmi Yoo
Advanced Materials Division, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Search for more papers by this authorKi Chul Kim
Department of Chemical Engineering, Konkuk University, 120, Neungdong-ro, Gwangjin-gu, Seoul, 05029 Republic of Korea
Search for more papers by this authorCorresponding Author
Dae Woo Kim
Department of Chemical and Biomolecular Engineering, Yonsei University, 50, Yonsei-ro, Seodaemun-gu, Seoul, 03722 Republic of Korea
E-mail: [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Kiwon Eum
Department of Chemical Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul, 06978 Republic of Korea
E-mail: [email protected]; [email protected]
Search for more papers by this authorAbstract
Filler morphology control is critical for enhancing the gas separation performance of mixed matrix membranes (MMMs). A vertical transport channel using the crystal twinning phenomenon is designed on the zeolitic imidazolate framework (ZIF) nanoplate. Twinned ZIF-8 (TZIF-8) nanoplate is prepared by controlling the shape of ZIF-L from nanosheet to twinned flake, followed by conversion into the ZIF-8 phase. With the addition of TZIF-8 in 6FDA-DAM polymer, propylene/propane selectivity is dramatically enhanced, showing propylene permeability of 40 Barrer and propylene/propane selectivity of 82. The separation performance surpasses the performance of MMMs reported so far, and the selectivity is comparable to that of polycrystalline ZIF-8 membranes. A transport mechanism study using mathematical models implies that the percolated twin fillers create rapid and selective gas channels for desired molecules and substantial tortuous pathways for undesired molecules.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
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| smtd202401248-sup-0001-SuppMat.docx6.9 MB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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