Donor–Acceptor Competition via Halide Vacancy Filling for Oxygen Detection of High Sensitivity and Stability by All-Inorganic Perovskite Films
Weiwei Xing
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorQianqian Yao
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorCorresponding Author
Wenpeng Zhu
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorHe Jiang
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorXiaoyue Zhang
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorYe Ji
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorJian Shao
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorWeiming Xiong
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorCorresponding Author
Biao Wang
Sino-French Institute of Nuclear Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082 China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorBangmin Zhang
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorXin Luo
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorCorresponding Author
Yue Zheng
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorWeiwei Xing
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorQianqian Yao
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorCorresponding Author
Wenpeng Zhu
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorHe Jiang
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorXiaoyue Zhang
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorYe Ji
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorJian Shao
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorWeiming Xiong
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorCorresponding Author
Biao Wang
Sino-French Institute of Nuclear Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082 China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorBangmin Zhang
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorXin Luo
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
Search for more papers by this authorCorresponding Author
Yue Zheng
School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
State Key Laboratory of Optoelectronic Materials and Technologies, Sun Yat-sen University, Guangzhou, 510275 China
Centre for Physical Mechanics and Biophysics, School of Physics, Sun Yat-sen University, Guangzhou, 510275 China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorAbstract
Oxygen detection by organic–inorganic halide perovskites (OIHPs) has demonstrated advantages in operating temperature, response time, and reversibility over traditional materials. However, OIHPs can only sense O2 in light and the unavoidable O2 exposure during detection easily induces the degradation of OIHPs. The trade-off between sensitivity and stability makes the OIHP-based oxygen sensors impractical. By replacing organic groups with Cs, the compact films of all-inorganic halide perovskites (AIHPs) that can adsorb O2 at grain boundaries in dark are developed. AIHPs show conductance increase of 1875.5% from 1 × 10−5 to 700 Torr of O2 pressure, associated with full reversibility and long-term stability. Combining experiments and modeling, this work reveals the donor–acceptor competition via halide vacancy filling leading to the modulation of carrier concentration and mobility. This work offers understandings on oxygen sensing by perovskite materials and paves the way for further optimization of AIHPs as promising oxygen sensors with high sensitivity and stability.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
| Filename | Description |
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| smll202102733-sup-0001-SuppMat.pdf3.7 MB | Supporting information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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