Confinement Growth of Layered WS2 in Hollow Beaded Carbon Nanofibers with Synergistic Anchoring Effect to Reinforce Li+/Na+ Storage Performance
Huayu Wu
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002 P. R. China
Search for more papers by this authorXing Chen
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002 P. R. China
Search for more papers by this authorChen Qian
College of Chemistry and Chemical Engineering, Yangzhou Polytechnic Institute, Yangzhou, 225127 P. R. China
Search for more papers by this authorCorresponding Author
Hui Yan
Department of Chemistry, University of Louisiana at Lafayette, Lafayette, LA, 70504 USA
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorChenyi Yan
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002 P. R. China
Search for more papers by this authorNuo Xu
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002 P. R. China
Search for more papers by this authorCorresponding Author
Yuanzhe Piao
Graduate School of Convergence Science and Technology, Seoul National University, 145 Gwanggyo-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16229 Republic of Korea
Advanced Institutes of Convergence Technology, Seoul National University, 145 Gwanggyo-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16229 Republic of Korea
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorGuowang Diao
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002 P. R. China
Search for more papers by this authorCorresponding Author
Ming Chen
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002 P. R. China
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin, 300071 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorHuayu Wu
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002 P. R. China
Search for more papers by this authorXing Chen
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002 P. R. China
Search for more papers by this authorChen Qian
College of Chemistry and Chemical Engineering, Yangzhou Polytechnic Institute, Yangzhou, 225127 P. R. China
Search for more papers by this authorCorresponding Author
Hui Yan
Department of Chemistry, University of Louisiana at Lafayette, Lafayette, LA, 70504 USA
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorChenyi Yan
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002 P. R. China
Search for more papers by this authorNuo Xu
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002 P. R. China
Search for more papers by this authorCorresponding Author
Yuanzhe Piao
Graduate School of Convergence Science and Technology, Seoul National University, 145 Gwanggyo-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16229 Republic of Korea
Advanced Institutes of Convergence Technology, Seoul National University, 145 Gwanggyo-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16229 Republic of Korea
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorGuowang Diao
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002 P. R. China
Search for more papers by this authorCorresponding Author
Ming Chen
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002 P. R. China
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin, 300071 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorAbstract
Novel nitrogen doped (N-doped) hollow beaded structural composite carbon nanofibers are successfully applied for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). Tungsten disulfide (WS2) nanosheets are confined, through synergistic anchoring, on the surface and inside of hollow beaded carbon nanofibers (HB CNFs) via a hydrothermal reaction method to construct the hierarchical structure HB WS2@CNFs. Benefiting from this unique advantage, HB WS2@CNFs exhibits remarkable lithium-storage performance in terms of high rate capability (≈351 mAh g−1 at 2 A g−1) and stable long-term cycle (≈446 mAh g−1 at 1 A g−1 after 100 cycles). Moreover, as an anode material for SIBs, HB WS2@CNFs obtains excellent long cycle life and rate performance. During the charging/discharging process, the evolution of morphology and composition of the composite are analyzed by a set of ex situ methods. This synergistic anchoring effect between WS2 nanosheets and HB CNFs is capable of effectively restraining volume expansion from the metal ions intercalation/deintercalation process and improving the cycling stability and rate performance in LIBs and SIBs.
Conflict of Interest
The authors declare no conflict of interest.
Supporting Information
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