The Influence of Complex Luminescence Centres on the Luminescent Properties of CaS: Eu
SU-142432 Chernogolovka, Moscow district, USSR.
Abstract
enPhotoluminescence, cathodoluminescence, and excitation spectra of CaS: Eu phosphors with different activator concentrations (0.1 to 2 at%) are measured at 4.2, 80, and 300 K. Excitation and luminescence bands originating from the associate centres Eu-VCa are observed in addition to those of a single Eu
centre. Calculations by the method of linear combination of atomic orbitals (LCAO) allow to obtain a scheme of the electron terms of the associates which is in good agreement with the experiment.
Abstract
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