Supercapacitor performance of binder-free buckypapers from multiwall carbon nanotubes synthesized at different temperatures
K. M. Popov
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Search for more papers by this authorV. E. Arkhipov
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Search for more papers by this authorA. G. Kurenya
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Search for more papers by this authorE. O. Fedorovskaya
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Novosibirsk State University, 2 Pirogova str., 630090 Novosibirsk, Russia
Search for more papers by this authorK. A. Kovalenko
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Search for more papers by this authorA. V. Okotrub
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Novosibirsk State University, 2 Pirogova str., 630090 Novosibirsk, Russia
Search for more papers by this authorCorresponding Author
L. G. Bulusheva
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Novosibirsk State University, 2 Pirogova str., 630090 Novosibirsk, Russia
Corresponding author: e-mail [email protected], Phone: +7 383 3305352, Fax: +7 383 3309489
Search for more papers by this authorK. M. Popov
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Search for more papers by this authorV. E. Arkhipov
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Search for more papers by this authorA. G. Kurenya
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Search for more papers by this authorE. O. Fedorovskaya
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Novosibirsk State University, 2 Pirogova str., 630090 Novosibirsk, Russia
Search for more papers by this authorK. A. Kovalenko
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Search for more papers by this authorA. V. Okotrub
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Novosibirsk State University, 2 Pirogova str., 630090 Novosibirsk, Russia
Search for more papers by this authorCorresponding Author
L. G. Bulusheva
Nikolaev Institute of Inorganic Chemistry, SB RAS, 3 Acad. Lavrentiev ave., 630090 Novosibirsk, Russia
Novosibirsk State University, 2 Pirogova str., 630090 Novosibirsk, Russia
Corresponding author: e-mail [email protected], Phone: +7 383 3305352, Fax: +7 383 3309489
Search for more papers by this authorAbstract
Multiwall carbon nanotubes (MWCNTs) have been synthesized by aerosol-assisted catalytic chemical vapor deposition method from a 2% ferrocene solution in toluene at temperatures of 720 and 800 °C. After an oxidation by a HNO3/H2SO4 mixture, MWCNTs were dispersed in water and deposited in form of buckypapers with a thickness of ∼150 μm. The obtained materials were used as working electrodes of supercapacitors without adding of binder. The electrode from MWCNTs synthesized at lower temperature showed the larger capacitance in 1 M H2SO4 and 6 M KOH electrolytes, especially at low scan rates. An increase of double-layer capacitance was due to larger specific surface and microporosity of the material; a gain in pseudocapacitance was attributed to larger quantity of oxygenated groups developed on the defective surface of nanotubes. The electrode showed a good cyclic performance during a repetitive charge/discharge test.
A larger specific capacitance of MWCNTs synthesized at 720 °C is related with etching of nanotube tips and higher oxygenation of nanotube surface as the result of binder-free buckypaper electrode preparation.
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