Synthesis of polymeric ionic liquid microsphere/Pt nanoparticle hybrids for electrocatalytic oxidation of methanol and catalytic oxidation of benzyl alcohol
Jianhu Yang
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China
Search for more papers by this authorLihua Qiu
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China
Search for more papers by this authorBaoqiang Liu
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China
Search for more papers by this authorYingjing Peng
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China
Search for more papers by this authorCorresponding Author
Feng Yan
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, ChinaSearch for more papers by this authorSongmin Shang
Institute of Textiles and Clothing, The Hong Kong Polytechnic University, Hong Kong, China
Search for more papers by this authorJianhu Yang
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China
Search for more papers by this authorLihua Qiu
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China
Search for more papers by this authorBaoqiang Liu
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China
Search for more papers by this authorYingjing Peng
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China
Search for more papers by this authorCorresponding Author
Feng Yan
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China
Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, ChinaSearch for more papers by this authorSongmin Shang
Institute of Textiles and Clothing, The Hong Kong Polytechnic University, Hong Kong, China
Search for more papers by this authorAbstract
Herein, we present a facile approach for the synthesis of polymeric ionic liquids (PILs) microspheres for metal scavenging and catalysis. Crosslinked poly(1-butyl-3-vinylimidazolium bromide) microspheres with the diameter of about 200 nm were synthesized via miniemulsion polymerization, in which 1,4-di(vinylimidazolium) butane bisbromide was added as the crosslinker. Anion exchange of PIL microspheres with Pt precursor and followed by the reduction of Pt ions produced PIL microsphere supported Pt nanoparticle hybrids. The synthesized Pt nanoparticles with a diameter of about 2 nm are uniformly dispersed and strongly bound to the surface of PIL microspheres. The catalytic performances of PIL/Pt nanoparticle hybrids were evaluated for both the electrocatalytic oxidation of methanol and oxidation of benzyl alcohol. The PIL/Pt nanoparticle hybrids show better electrocatalytic activity towards the electrooxidation of methanol than pure Pt nanoparticles. Furthermore, they are effective and easily reusable catalysts for the selective oxidation of benzyl alcohol in aqueous reaction media, demonstrating that the synthesized PIL microspheres are suitable scaffolds for heterogeneous catalysts Pt. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011
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