Facile, Direct, De Novo Synthesis of an Alkyl Phosphoric Acid-Decorated Covalent Organic Framework
Shengdong Wang
State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou, 510640 P. R. China
Search for more papers by this authorXiaohui Tang
State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou, 510640 P. R. China
Search for more papers by this authorKaijie Yang
MOE Key Laboratory for Soft Chemistry and Functional Materials, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094 P. R. China
Search for more papers by this authorBin Chen
State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou, 510640 P. R. China
Search for more papers by this authorKun Zhang
MOE Key Laboratory for Soft Chemistry and Functional Materials, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094 P. R. China
Search for more papers by this authorHong Xu
Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing, 100084 P. R. China
Search for more papers by this authorWeitao Wang
State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou, 510640 P. R. China
Search for more papers by this authorCorresponding Author
Gen Zhang
MOE Key Laboratory for Soft Chemistry and Functional Materials, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094 P. R. China
E-mail: [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Cheng Gu
State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou, 510640 P. R. China
Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates, South China University of Technology, Guangzhou, 510640 P. R. China
E-mail: [email protected]; [email protected]
Search for more papers by this authorShengdong Wang
State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou, 510640 P. R. China
Search for more papers by this authorXiaohui Tang
State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou, 510640 P. R. China
Search for more papers by this authorKaijie Yang
MOE Key Laboratory for Soft Chemistry and Functional Materials, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094 P. R. China
Search for more papers by this authorBin Chen
State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou, 510640 P. R. China
Search for more papers by this authorKun Zhang
MOE Key Laboratory for Soft Chemistry and Functional Materials, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094 P. R. China
Search for more papers by this authorHong Xu
Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing, 100084 P. R. China
Search for more papers by this authorWeitao Wang
State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou, 510640 P. R. China
Search for more papers by this authorCorresponding Author
Gen Zhang
MOE Key Laboratory for Soft Chemistry and Functional Materials, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094 P. R. China
E-mail: [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Cheng Gu
State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou, 510640 P. R. China
Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates, South China University of Technology, Guangzhou, 510640 P. R. China
E-mail: [email protected]; [email protected]
Search for more papers by this authorAbstract
The development and understanding of proton conductors based on phosphoric acid are critical for the field of chemistry, biology, and energy. Covalent organic frameworks (COFs), featuring highly crystalline structures and controllable pore sizes, are suitable for constructing phosphoric acid-based proton conductors. However, because of tedious and intricate synthesis, how to develop COFs based on phosphoric acid remains a substantial challenge. Herein, a side-chain decorated strategy is contributed to construct a phosphoric acid-functionalized, imine-linked COF by de novo synthesis. The phosphoric acid side chains with vigorous motion integrating with 1D nanochannels endow the resulting COF with intrinsic proton conductivity. This work expectantly provides a competitive alternative for producing phosphoric acid-functionalized COFs with high intrinsic proton conductivity.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
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| marc202200678-sup-0001-SuppMat.pdf2.5 MB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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