Photochromic Copolymers Containing Bisthienylethene Units
Sheng Wang
Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237 P. R. China
Search for more papers by this authorXiaochuan Li
Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237 P. R. China
Search for more papers by this authorBingzhi Chen
Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237 P. R. China
Search for more papers by this authorQianfu Luo
Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237 P. R. China
Search for more papers by this authorCorresponding Author
He Tian
Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237 P. R. China
Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237 P. R. China. Fax: +86-21-64252288Search for more papers by this authorSheng Wang
Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237 P. R. China
Search for more papers by this authorXiaochuan Li
Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237 P. R. China
Search for more papers by this authorBingzhi Chen
Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237 P. R. China
Search for more papers by this authorQianfu Luo
Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237 P. R. China
Search for more papers by this authorCorresponding Author
He Tian
Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237 P. R. China
Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai, 200237 P. R. China. Fax: +86-21-64252288Search for more papers by this authorAbstract
Summary: Two simple yet effective strategies (Wittig condensation reaction and radical polymerization) for the synthesis of photochromic copolymers containing bisthienylethene units are presented. A new family of photochromic copolymer containing bisthienylethene and fluorophores units in the main chains was synthesized by Wittig condensation reaction. Another novel photochromic copolymer with multi-component photochromic pendent groups was prepared by radical polymerization. Photochromism of the copolymers was investigated in solid film and in solution.
References
- 1 M. Irie, Chem. Rev. 2000, 100, 1685.
- 2 H. Tian, S. J. Yang, Chem. Soc. Rev. 2004, 33, 85.
- 3
B. L. Feringa, Ed.,
“ Molecular Switches”,
Wiley-VCH,
Weinheim
2001.
10.1002/3527600329 Google Scholar
- 4 H. Tian, B. Z. Chen, H. Y. Tu, K. Müllen, Adv. Mater. 2002, 14, 918.
- 5
- 5a T. J. Wigglesworth, N. R. Branda, Adv. Mater. 2004, 16, 123;
- 5b A. J. Myles, N. R. Branda, Macromolecules 2003, 36, 298.
- 6
- 6a H. Tian, H. Y. Tu, Adv. Mater. 2000, 12, 1597;
- 6b T. B. Norsten, N. R. Branda, J. Am. Chem. Soc. 2001, 123, 1784.
- 7 K. Uchida, A. Takata, M. Saito, A. Murakami, S. Nakamura, M. Irie, Adv. Mater. 2003, 15, 785.
- 8 F. Stellacci, C. Bertarelli, G. Zerbi, Adv. Mater. 1999, 11, 292.
- 9
- 9a A. Peters, N. R. Branda, Adv. Mater. Opt. Electron. 2000, 10, 245;
- 9b T. Kaieda, S. Kobatake, H. Miyasaka, M. Murakami, N. Iwai, Y. Nagata, A. Itaya, M. Irie, J. Amer. Chem. Soc. 2004, 124, 2015.
- 10 H. Cho, E. Kim, Macromolecules 2002, 35, 8684.
- 11 M. Morimoto, S. Kobatake, M. Irie, Adv. Mater. 2002, 14, 1027.
- 12 L. N. Lucas, J. J. de Jong, J. H. van Esch, R. M. Kellogg, B. L. Feringa, Eur. J. Org. Chem. 2003, 155.
- 13
- 13a A. Osuka, D. Fujikane, H. Shinmori, S. Kobatake, M. Irie, J. Org. Chem. 2001, 66, 3913;
- 13b Y. Yokohama, T. Goto, T. Inoue, M. Yokoyama, Y. Kurita, Chem. Lett. 1988, 1049;
- 13c M. Irie, K. Sakemura, M. Okinaka, K. Uchida, J. Org. Chem. 1995, 60, 8305.
- 14
- 14a S. Kawai, T. Kunitake, M. Irie, Chem. Lett. 1999, 905;
- 14b T. Kawai, T. Sasaki, M. Irie, Chem. Commun. 2001, 711.
- 15 I. Pang, J. Li, B. Hu, F. E. Karasz, Macromolecules 1999, 32, 3946.
- 16 J.-S. Yang, C.-S. Lin, C.-Y. Hwang, Org. Lett. 2001, 3(6), 889.
- 17 P. Ghosh, P. K. Bharawaj, J. Am. Chem. Soc. 1996, 118, 10579.
- 18 M. Irie, T. Erighchi, T. Takada, K. Uchida, Tetrahedron 1997, 53, 12263.