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Moisture-curable rubbers, 4^†. Moisture-cure of chloroprene rubber

Corresponding Author

Shinzo Yamashita

Department of Chemistry, Kyoto Institute of Technology, Matsugasaki, Sakyo, Kyoto 606, Japan

Department of Chemistry, Kyoto Institute of Technology, Matsugasaki, Sakyo, Kyoto 606, JapanSearch for more papers by this author

Yuichi Nakawaki,

Yuichi Nakawaki

Department of Chemistry, Kyoto Institute of Technology, Matsugasaki, Sakyo, Kyoto 606, Japan

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Akinori Kidera,

Akinori Kidera

Department of Chemistry, Kyoto Institute of Technology, Matsugasaki, Sakyo, Kyoto 606, Japan

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Shinzo Yamashita,

Corresponding Author

Shinzo Yamashita

Department of Chemistry, Kyoto Institute of Technology, Matsugasaki, Sakyo, Kyoto 606, Japan

Department of Chemistry, Kyoto Institute of Technology, Matsugasaki, Sakyo, Kyoto 606, JapanSearch for more papers by this author

Yuichi Nakawaki,

Yuichi Nakawaki

Department of Chemistry, Kyoto Institute of Technology, Matsugasaki, Sakyo, Kyoto 606, Japan

Search for more papers by this author

Akinori Kidera,

Akinori Kidera

Department of Chemistry, Kyoto Institute of Technology, Matsugasaki, Sakyo, Kyoto 606, Japan

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First published: November 1987

https://doi.org/10.1002/macp.1987.021881107

Citations: 4

^†

Part 3: cf.⁴.

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Abstract

Chloroprene rubber (CR) was allowed to react with 3-aminopropyltriethoxysilane (APS) and then cured by soaking in hot water. The moisture-cured rubber showed a network-chain density of 3,6·10⁻⁴ mol·cm⁻³ and a tensile strength at break of 10 MPa. The reaction of CR with APS was found to be a Menshutkin reaction. The activation energy and the frequency factor were 59 kJ·mol⁻¹ and 4,3·10⁴ l·mol⁻¹·s⁻¹, respectively.

References

1 S. Yamashita, M. Shigaraki, M. Orita, J. Nishimura, K. Sato, Rev. Gen. Caoutch. Plast. 606, 126 (1980)
CAS Google Scholar
2 S. Yamashita, A. Yamada, M. Ohata, S. Kohjiya, Makromol. Chem. 186, 1373 (1985)
10.1002/macp.1985.021860704
CAS Web of Science® Google Scholar
3 S. Yamashita, A. Yamada, M. Ohata, S. Kohjiya, Makromol. Chem. 186, 2269 (1985)
10.1002/macp.1985.021861107
CAS Web of Science® Google Scholar
4 A. Yamada, Y, Shiokaramatsu, S. Yamashita, Makromol. Chem. 186, 2275 (1985)
10.1002/macp.1985.021861108
CAS Web of Science® Google Scholar
5 A. M. Neal, L. R. Mayo, “ Neoprene”, in “ Synthetic Rubber”, edited by G. S. Whitby, C. C. Davis, and R. F. Dunbrook, John Wiley & Sons, Inc., New York 1954, p. 767
Google Scholar
6 R. Pariser, Kunststoffe 50, 623 (1960)
CAS Google Scholar
7 P. J. Flory, J. Rehner, Jr., J. Chem. Phys. 11, 521 (1943);
10.1063/1.1723792
CAS Web of Science® Google Scholar
P. J. Flory, J. Chem. Phys. 18, 108 (1950)
10.1063/1.1747424
CAS Web of Science® Google Scholar
8 G. M. Bristow, W. F. Watson, Trans. Faraday Soc. 54, 1731 (1958)
10.1039/TF9585401731
CAS Web of Science® Google Scholar
9 A. G. Stevenson, in “ Vulcanization of Elastomers”, edited by G. Alliger and I. J. Sjothun, Rheinhold, New York 1964, p. 271
Google Scholar
10 A. V. Tongerloo, R. Vukov, “Proceedings of the International Rubber Conference”, Venice 1979, p. 70
Google Scholar
11 E. A. Moelwyn-Hughes, “ The Kinetics of Reactions in Solution”, 2nd edition, Oxford Univ. Press, London 1947, p. 70, 73
Google Scholar

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Volume188, Issue11

November 1987

Pages 2553-2557

Moisture-curable rubbers, 4^†. Moisture-cure of chloroprene rubber

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Moisture-curable rubbers, 4†. Moisture-cure of chloroprene rubber

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Moisture-curable rubbers, 4^†. Moisture-cure of chloroprene rubber