The reactions of hexachlorocyclotriphosphazene N₃P₃Cl₆ (1) with 1-naphthol and 1-naphthylamine have been examined. The reaction of 1 with sodium 1-naphthoxy gave the hexakis(1-naphthoxy)cyclotriphosphazene (2) in high yield. Geminal 2,2-di(1-naphthylamino)-4,4,6,6-tetrachlorocyclotriphosphazene (3) was obtained from the reaction of 1 with 1-naphthylamine. The structures of phosphazene derivatives were defined by elemental analysis, FTIR, UV--visible, and ¹H, ¹³C, ³¹P NMR spectroscopy. The fluorescence intensity of the compounds was measured in THF and CH₂Cl₂. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:158–162, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20400

REFERENCES

1 Jaeger, R. De.; Gleria, M. Phosphazenes: A Worldwide Insight; NOVA Science Publishers: New York, 2005; Ch. 1.
Google Scholar
2 Allcock, H. R. Phosphorus, Sulfur, Silicon 2004, 179, 661–671.
10.1080/10426500490426386
CAS Web of Science® Google Scholar
3 Gleria, M.; Jaeger, R. J Inorg Organomet Polym 2001, 11, 1–45.
10.1023/A:1013276518701
CAS Web of Science® Google Scholar
4 Allcock, H. R.; Kelam, E. C. Solid State Ionics 2003, 156(3), 401–414.
10.1016/S0167-2738(02)00694-X
CAS Web of Science® Google Scholar
5 Jaeger, R. D.; Gleria, M. Prog Polym Sci 1998, 23, 119–216.
10.1016/S0079-6700(97)00027-0
Web of Science® Google Scholar
6 Zhou, X. Y.; Weston, J.; Chalkova, E.; Hofmann, M. A.; Ambler, C. M.; Allcock, H. R.; Lvov, S. N. Electrochim Acta 2003, 48(14–16), 2173–2180.
10.1016/S0013-4686(03)00201-9
CAS Web of Science® Google Scholar
7 Lyon, R. E.; Speitel, L.; Walters, R. N.; Crowley, S. Fire Mater 2003, 27, 195–208.
10.1002/fam.828
CAS Web of Science® Google Scholar
8 Thomas, K. R. J.; Chandrasekhar, V.; Zanello, P.; Laschi, F. Polyhedron 1997, 16, 1003–1011.
10.1016/S0277-5387(96)00385-3
CAS Web of Science® Google Scholar
9 Potin, P. H.; Jaeger, R. D. Eur Polym J 1991, 27(4/5), 341–348.
10.1016/0014-3057(91)90185-Q
CAS Web of Science® Google Scholar
10 Chattopadhyay, N.; Haldar, B.; Mallick, A.; Sengupta, S. Tetrahedron Lett 2005, 46, 3089–3092.
10.1016/j.tetlet.2005.03.006
CAS Web of Science® Google Scholar
11 Carriedo, G. A.; Alonso, F. J. G.; Alvarez, J. L. G.; Soto, A. P. Inorg Chim Acta 2005, 38, 1850–1856.
10.1016/j.ica.2004.10.020
CAS Web of Science® Google Scholar
12 Ye, C.; Zhang, Z.; Liu, W. Synth Commun 2002, 32, 203–209.
10.1081/SCC-120002003
CAS Web of Science® Google Scholar
13 Beşli, S.; Coles, S. J.; Davies, D. B.; Eaton, R. J.; Hursthouse, M. B.; Kılıç, A.; Shaw, R. A. Eur J Inorg Chem 2005, 5, 959–966.
Google Scholar
14 Marco, P. G.; Giro, G.; Gleria, M.; Lora, S. Thin Solid Films 1986, 135, 157–164.
10.1016/0040-6090(86)90122-7
Web of Science® Google Scholar
15 Bravo, J.; Tarazona, M. P.; Saiz, E. Macromolecules 1992, 25, 5625–5631.
10.1021/ma00047a011
CAS Web of Science® Google Scholar
16 Wu, X.; Fang, C.; Cheng, X.; Cao, D.; Liu, Z.; Wang, M.; Wang, Z. J Mater Sci Lett 2002, 21, 1767–1768.
10.1023/A:1020929022585
CAS Web of Science® Google Scholar
17 Gleria, M.; Barigelletti, F.; Dellonte, S.; Lora, S.; Minto F.; Bortolus, P. Chem Phys Lett 1981, 83, 559–563.
10.1016/0009-2614(81)85522-4
CAS Web of Science® Google Scholar
18 Günseli, T.; Odabaşoǧlu, M. Dyes Pigm 2006, 70, 117–125.
10.1016/j.dyepig.2005.05.005
CAS Web of Science® Google Scholar
19 Gleria, M.; Minto, F.; Flamigni, L. US Patent 5, 260, 103, 1993.
Google Scholar
20 Allen, C. W. Chem Rev 1991, 91, 119–135.
10.1021/cr00002a002
CAS Web of Science® Google Scholar
21 Wu H. S.; Meng S. S. Ind Eng Chem Res 1998, 37(2), 675–683.
10.1021/ie970565c
CAS Web of Science® Google Scholar

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Synthesis, characterization, and fluorescence phenomena of 1-naphthoxy and 1-naphthylamino substituted cyclotriphosphazenes

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Synthesis, characterization, and fluorescence phenomena of 1-naphthoxy and 1-naphthylamino substituted cyclotriphosphazenes

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