A convenient synthesis of thiamacrocyclic dilactams
Ashraf A. Abbas
Chemistry Department, Faculty of Science, Cairo University, Giza, Egypt
Search for more papers by this authorCorresponding Author
Adel S. Girgis
Pesticide Chemistry Department, National Research Centre, Dokki, 12622 Cairo, Egypt
Pesticide Chemistry Department, National Research Centre, Dokki, 12622 Cairo, EgyptSearch for more papers by this authorAshraf A. Abbas
Chemistry Department, Faculty of Science, Cairo University, Giza, Egypt
Search for more papers by this authorCorresponding Author
Adel S. Girgis
Pesticide Chemistry Department, National Research Centre, Dokki, 12622 Cairo, Egypt
Pesticide Chemistry Department, National Research Centre, Dokki, 12622 Cairo, EgyptSearch for more papers by this authorAbstract
A convenient synthesis of 26- to 28-membered thiamacrocyclic dilactams 8 was achieved via base-catalyzed condensation reaction of bis-2-cyanoacetamides 4 with dialdehyde derivatives 7. The reaction was assumed to be geometrically stereoselective, affording E, E′-configuration as the only isolable isomer. N, N′-[Alkanediylbis(thia-2,1-phenylene)]bis[2-cyanoacetamides] 4 were obtained by the reaction of cyanoacetic acid with the corresponding diamine hydrochlorides 3. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:249–254, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20292
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