Polymer Electron Acceptors Based on Fluorinated Isoindigo Unit for Polymer Solar Cells†
Junhui Miao
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China
University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorHan Xu
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China
Center for Advanced Optoelectronic Functional Materials Research, Northeast Normal University, Changchun, Jilin 130024 China
Search for more papers by this authorCorresponding Author
Bin Meng
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China
E-mail: [email protected] (B.M.); [email protected] (J.L.)Search for more papers by this authorCorresponding Author
Jun Liu
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China
E-mail: [email protected] (B.M.); [email protected] (J.L.)Search for more papers by this authorLixiang Wang
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China
Search for more papers by this authorJunhui Miao
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China
University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorHan Xu
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China
Center for Advanced Optoelectronic Functional Materials Research, Northeast Normal University, Changchun, Jilin 130024 China
Search for more papers by this authorCorresponding Author
Bin Meng
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China
E-mail: [email protected] (B.M.); [email protected] (J.L.)Search for more papers by this authorCorresponding Author
Jun Liu
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China
E-mail: [email protected] (B.M.); [email protected] (J.L.)Search for more papers by this authorLixiang Wang
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 China
Search for more papers by this authorAbstract
Most of efficient polymer electron acceptors for polymer solar cells (PSCs) are based on naphthalene diimide or perylene diimide as the electron deficient building block. In this paper, for the first time, we report polymer electron acceptors based on fluorinated isoindigo (F-IID) as the electron deficient building block. We synthesized two polymer electron acceptors consisting of alternating F-IID unit and thiophene/selenophen unit. They show low-lying LUMO/HOMO energy levels of –3.69/–5.69 eV, high electron mobilities of 1.31×10–5 cm2·V–1·s–1 and broad absorption spectra with the optical bandgap of 1.61 eV. PSC devices using the two F-IID-based polymers as polymer electron acceptors show encouraging power conversion efficiencies (PCEs) of up to 1.50% with an open-circuit voltage (VOC) of 0.97 V, a short-circuit current density (JSC) of 2.91 mA·cm–2, and a fill factor (FF) of 53.2%. This work suggests a new kind of polymer electron acceptors based on F-IID unit.
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