Full Paper

Free Access

Structural Dependence of Competitive Adsorption of Water and Methanol on TiO₂ Surfaces

Zhengming Wang

Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Material for Energy Conversion, and Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui 230026, China

Search for more papers by this author

Feng Xiong,

Feng Xiong

Search for more papers by this author

Guanghui Sun,

Guanghui Sun

Search for more papers by this author

Yuekang Jin,

Yuekang Jin

Search for more papers by this author

Weixin Huang,

Corresponding Author

Weixin Huang

[email protected]

E-mail: [email protected]Search for more papers by this author

Zhengming Wang,

Zhengming Wang

Search for more papers by this author

Feng Xiong,

Feng Xiong

Search for more papers by this author

Guanghui Sun,

Guanghui Sun

Search for more papers by this author

Yuekang Jin,

Yuekang Jin

Search for more papers by this author

Weixin Huang,

Corresponding Author

Weixin Huang

[email protected]

E-mail: [email protected]Search for more papers by this author

First published: 08 May 2017

https://doi.org/10.1002/cjoc.201600738

Citations: 12

In Memory of Professor Enze Min.

About

PDF

Tools

Share a link

Email
Wechat
Bluesky

Abstract

Employing TiO₂ anatase (001)-(1 × 4), rutile (110) and rutile (011)-(2 × 1) single crystal surfaces, we comprehensively studied the effects of TiO₂ surface structures on the competitive adsorption of water and methanol by means of low energy electron diffraction, thermal desorption spectra and X-ray photoelectron spectroscopy. The relative adsorption strengths of chemisorbed methanol and water vary with the TiO₂ surface structures and the adsorption sites. This leads to TiO₂ surface structure-dependent competitive adsorption of water and methanol. The chemisorption of CH₃OH on TiO₂ anatase (001)-(1 × 4) surface is seldom affected by pre-covered water at low coverages but is affected by pre-covered water at high coverages; the chemisorption of CH₃OH on TiO₂ rutile (110) surface is seldom affected by pre-covered water; and the chemisorption of CH₃OH on TiO₂ rutile (011)-(2 × 1) surface is affected by pre-covered water even at low coverages. These results deepen the fundamental understandings of surface chemistry on TiO₂ surfaces.

References

1Ma, Y.; Wang, X.; Jia, Y.; Chen, X.; Han, H.; Li, C. Chem. Rev. 2014, 114, 9987.
10.1021/cr500008u
CAS PubMed Web of Science® Google Scholar
2Yang, H. G.; Sun, C. H.; Qiao, S. Z.; Zou, J.; Liu, G.; Smith, S. C.; Cheng, H. M.; Lu, G. Q. Nature 2008, 453, 638.
10.1038/nature06964
CAS PubMed Web of Science® Google Scholar
3Liu, G.; Yang, H. G.; Pan, J.; Yang, Y. Q.; Lu, G. Q.; Cheng, H.-M. Chem. Rev. 2014, 114, 9559.
10.1021/cr400621z
CAS PubMed Web of Science® Google Scholar
4Chen, S.; Li, D.; Liu, Y.; Huang, W. J. Catal. 2016, 341, 126.
10.1016/j.jcat.2016.06.016
CAS Web of Science® Google Scholar
5Takahashi, H.; Watanabe, R.; Miyauchi, Y.; Mizutani, G. J. Chem. Phys. 2011, 134, 154704.
10.1063/1.3578178
CAS PubMed Web of Science® Google Scholar
6Linsebigler, A. L.; Lu, G.; Yates Jr, J. T. Chem. Rev. 1995, 95, 735.
10.1021/cr00035a013
CAS PubMed Web of Science® Google Scholar
7Thompson, T. L.; Yates, J. T. Chem. Rev. 2006, 106, 4428.
10.1021/cr050172k
CAS PubMed Web of Science® Google Scholar
8Diebold, U. Surf. Sci. Rep. 2003, 48, 53.
10.1016/S0167-5729(02)00100-0
CAS Web of Science® Google Scholar
9He, Y. B.; Li, W. K.; Gong, X. Q.; Dulub, O.; Selloni, A.; Diebold, U. J. Phys. Chem. C 2009, 113, 10329.
10.1021/jp903017x
CAS Web of Science® Google Scholar
10Brookes, I.; Muryn, C.; Thornton, G. Phys. Rev. Lett. 2001, 87, 266103.
10.1103/PhysRevLett.87.266103
CAS PubMed Web of Science® Google Scholar
11Bikondoa, O.; Pang, C. L.; Ithnin, R.; Muryn, C. A.; Onishi, H.; Thornton, G. Nature Mater. 2006, 5, 189.
10.1038/nmat1592
CAS Web of Science® Google Scholar
12Di Valentin, C.; Tilocca, A.; Selloni, A.; Beck, T.; Klust, A.; Batzill, M.; Losovyj, Y.; Diebold, U. J. Am. Chem. Soc. 2005, 127, 9895.
10.1021/ja0511624
CAS PubMed Web of Science® Google Scholar
13Zhang, Z.; Bondarchuk, O.; White, J.; Kay, B. D.; Dohnálek, Z. J. Am. Chem. Soc. 2006, 128, 4198.
10.1021/ja058466a
CAS PubMed Web of Science® Google Scholar
14Zhou, C.; Ren, Z.; Tan, S.; Ma, Z.; Mao, X.; Dai, D.; Fan, H.; Yang, X.; LaRue, J.; Cooper, R. Chem. Sci. 2010, 1, 575.
10.1039/c0sc00316f
CAS Web of Science® Google Scholar
15Herman, G. S.; Dohnalek, Z.; Ruzycki, N.; Diebold, U. J. Phys. Chem. B 2003, 107, 2788.
10.1021/jp0275544
CAS Web of Science® Google Scholar
16Guo, Q.; Xu, C.; Ren, Z.; Yang, W.; Ma, Z.; Dai, D.; Fan, H.; Minton, T. K.; Yang, X. J. Am. Chem. Soc. 2012, 134, 13366.
10.1021/ja304049x
CAS PubMed Web of Science® Google Scholar
17Yuan, Q.; Wu, Z.; Jin, Y.; Xu, L.; Xiong, F.; Ma, Y.; Huang, W. J. Am. Chem. Soc. 2013, 135, 5212.
10.1021/ja400978r
CAS PubMed Web of Science® Google Scholar
18Henderson, M. A.; Otero-Tapia, S.; Castro, M. E. Faraday Discuss. 1999, 114, 313.
10.1039/a902070e
CAS Web of Science® Google Scholar
19Shen, M.; Henderson, M. A. J. Phys. Chem. C 2012, 116, 18788.
10.1021/jp3046774
CAS Web of Science® Google Scholar
20Bates, S.; Gillan, M.; Kresse, G. J. Phys. Chem. B 1998, 102, 2017.
10.1021/jp9804998
CAS Web of Science® Google Scholar
21Oviedo, J.; Sánchez-de-Armas, R.; San Miguel, M. Á.; Sanz, J. F. J. Phys. Chem. C 2008, 112, 17737.
10.1021/jp805759y
CAS Web of Science® Google Scholar
22Sánchez, V. M.; Cojulun, J. A.; Scherlis, D. A. J. Phys. Chem. C 2010, 114, 11522.
10.1021/jp102361z
CAS Web of Science® Google Scholar
23de Armas, R. S.; Oviedo, J.; San Miguel, M.; Sanz, J. J. Phys. Chem. C 2007, 111, 10023.
10.1021/jp0717701
CAS Web of Science® Google Scholar
24Mao, X. C.; Wang, Z. Q.; Lang, X. F.; Hao, Q. Q.; Wen, B.; Dai, D. X.; Zhou, C. Y.; Liu, L. M.; Yang, X. M. J. Phys. Chem. C 2015, 119, 6121.
10.1021/acs.jpcc.5b00503
CAS Web of Science® Google Scholar
25Wang, C.-y.; Groenzin, H.; Shultz, M. J. J. Am. Chem. Soc. 2004, 126, 8094.
10.1021/ja048165l
CAS PubMed Web of Science® Google Scholar
26Xu, C.; Yang, W.; Guo, Q.; Dai, D.; Chen, M.; Yang, X. Chin. J. Catal. 2014, 35, 416.
10.1016/S1872-2067(14)60006-1
CAS Web of Science® Google Scholar
27Xiong, F.; Yu, Y.-Y.; Wu, Z.; Sun, G.; Ding, L.; Jin, Y.; Gong, X.-Q.; Huang, W. Angew. Chem., Int. Ed. 2016, 55, 623.
10.1002/anie.201509021
CAS PubMed Web of Science® Google Scholar
28Liang, Y.; Gan, S.; Chambers, S. A.; Altman, E. I. Phys. Rev. B 2001, 63, 235402.
10.1103/PhysRevB.63.235402
CAS Web of Science® Google Scholar
29Herman, G.; Sievers, M.; Gao, Y. Phys. Rev. Lett. 2000, 84, 3354.
10.1103/PhysRevLett.84.3354
CAS PubMed Web of Science® Google Scholar
30Guo, Q.; Zhou, C.; Ma, Z.; Ren, Z.; Fan, H.; Yang, X. Chem. Soc. Rev. 2016, 45, 3701.
10.1039/C5CS00448A
CAS PubMed Web of Science® Google Scholar
31Gong, X.-Q.; Khorshidi, N.; Stierle, A.; Vonk, V.; Ellinger, C.; Dosch, H.; Cheng, H.; Selloni, A.; He, Y.; Dulub, O. Surf. Sci. 2009, 603, 138.
10.1016/j.susc.2008.10.034
CAS Web of Science® Google Scholar
32Henderson, M. A. Langmuir 1996, 12, 5093.
10.1021/la960360t
CAS Web of Science® Google Scholar

Citing Literature

Volume35, Issue6

Special Issue:Dedicated to the Memory of Professor Enze Min (II)

June, 2017

Pages 889-895

Structural Dependence of Competitive Adsorption of Water and Methanol on TiO₂ Surfaces

Abstract

References

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

Structural Dependence of Competitive Adsorption of Water and Methanol on TiO2 Surfaces

Abstract

References

Citing Literature

References

Related

Information

Structural Dependence of Competitive Adsorption of Water and Methanol on TiO₂ Surfaces