Communication
PEG Click-Triazole Palladacycle: An Efficient Precatalyst for Palladium-Catalyzed Suzuki-Miyaura and Copper-free Sonogashira Reactions in Neat Water
Guofu Zhang,
Wei Zhang,
Yuxin Luan,
Xingwang Han,
Chengrong Ding,
Guofu Zhang
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
Search for more papers by this authorWei Zhang
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
Search for more papers by this authorYuxin Luan
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
Search for more papers by this authorXingwang Han
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
Search for more papers by this authorCorresponding Author
Chengrong Ding
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China, Tel.: 0086-0571-88320147; Fax: 0086-0571-88320147Search for more papers by this authorGuofu Zhang,
Wei Zhang,
Yuxin Luan,
Xingwang Han,
Chengrong Ding,
Guofu Zhang
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
Search for more papers by this authorWei Zhang
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
Search for more papers by this authorYuxin Luan
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
Search for more papers by this authorXingwang Han
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
Search for more papers by this authorCorresponding Author
Chengrong Ding
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China, Tel.: 0086-0571-88320147; Fax: 0086-0571-88320147Search for more papers by this authorAbstract
A novel water-soluble, phosphine-free PEG "click" triazole palladacycle has been successfully synthesized. As a precatalyst, the palladacycle exhibited superior catalytic activity towards Suzuki-Miyaura and copper-free Sonogashira cross-coupling in neat water with the turnover numbers (TONs) of up to 9.8×105. In addition, the catalyst could be reused at least 3 times without significant loss of reactivity.
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