CdTe-paper-based Visual Sensor for Detecting Methyl Viologen
Yingchun Su
State Key Laboratory of Urban Water Resource and Environment, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang 150001, China
Search for more papers by this authorShenghua Ma
State Key Laboratory of Urban Water Resource and Environment, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang 150001, China
Search for more papers by this authorKunpeng Jiang
State Key Laboratory of Urban Water Resource and Environment, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang 150001, China
Search for more papers by this authorCorresponding Author
Xiaojun Han
State Key Laboratory of Urban Water Resource and Environment, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang 150001, China
State Key Laboratory of Urban Water Resource and Environment, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang 150001, ChinaSearch for more papers by this authorYingchun Su
State Key Laboratory of Urban Water Resource and Environment, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang 150001, China
Search for more papers by this authorShenghua Ma
State Key Laboratory of Urban Water Resource and Environment, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang 150001, China
Search for more papers by this authorKunpeng Jiang
State Key Laboratory of Urban Water Resource and Environment, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang 150001, China
Search for more papers by this authorCorresponding Author
Xiaojun Han
State Key Laboratory of Urban Water Resource and Environment, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang 150001, China
State Key Laboratory of Urban Water Resource and Environment, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang 150001, ChinaSearch for more papers by this authorAbstract
This study developed a method on detecting methyl viologen (paraquat) using a CdTe-paper-based visual sensor. The CdTe Qdots were immobilized on the paper using glycerin. The volume percentages of CdTe in glycerin were optimized to be 50%. The sensing principle is that the methyl viologen quenches the fluorescence intensity of CdTe Qdots in a concentration dependent manner. The sensor is linearly response to the logarithm concentration of the methyl viologen in the range from 0.39 µmol/L to 3.89 mmol/L with a detection limit of 0.16 µmol/L and the correlation coefficient R2 of 0.99. Three parallel experiments at the methyl viologen concentration of 38.89 µmol/L give a relative error of 2.45%, which indicates a good reproducibility. The sensor is not disturbed by other pestisides including omethoate, anilofos, machete and glyphosate isopropylamine salt. The advantages of this sensor are disposable, stable, convenient, and easy to operate.
Supporting Information
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
| Filename | Description |
|---|---|
| cjoc_201400715_sm_suppl.pdf28.5 KB | suppl |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
REFERENCES
- 1 Porel, M.; Klimczak, A.; Freitag, M.; Galoppini, E.; Ramamurthy, V.. Langmuir, 2012, 28, 3355.
- 2 Huang, Y. D.; Huo, P.; Shao, M. Y.; Yin, J. X.; Shen, W. C.; Zhu, Q. Y.; Dai, J.. Inorg. Chem., 2014, 53, 3480.
- 3 Baltazar, T.; Dinis-Oliveira, R. J.; Duarte, J. A.; Bastos, M. D.; Carvalho, F.. Br. J. Pharmacol., 2013, 168, 44.
- 4 Gao, R.; Choi, N.; Chang, S. I.; Kang, S. H.; Song, J. M.; Cho, S. I.; Lim, D. W.; Choo, J.. Anal. Chim. Acta, 2010, 681, 87.
- 5 Ribeiro, J. A.; Carreira, C. A.; Lee, H. J.; Silva, F.; Martins, A.; Pereira, C. M.. Electrochim. Acta, 2010, 55, 7892.
- 6 Kenne Dedzo, G.; Nanseu-Njiki, C. P.; Ngameni, E.. Talanta, 2012, 99, 478.
- 7 Valera, E.; García-Febrero, R.; Pividori, I.; Sánchez-Baeza, F.; Marco, M. P.. Sensors Actuat. B-Chem., 2014, 194, 353.
- 8 Kishikawa, N.; Higuchi, S.; Ohyama, K.; Nakashima, K.; Kuroda, N.. Forensic Toxicology, 2013, 31, 301.
- 9 Yao, Z.; Hu, X.; Ma, W.; Chen, X.; Zhang, L.; Yu, J.; Zhao, Y.; Wu, H. C.. Analyst, 2013, 138, 5572.
- 10 Chen, K.; Liu, M.; Zhao, G.; Shi, H.; Fan, L.; Zhao, S.. Environ. Sci. Technol., 2012, 46, 11955.
- 11 Chen, H.; Yang, H.; Xu, W. C.; Tan, Y. B.. Chin. Chem. Lett., 2013, 24, 857.
- 12 Kim, J. H.; Mun, S.; Ko, H. U.; Yun, G. Y.; Kim, J.. Nanotechnology, 2014, 25, 092001.
- 13 Arena, A.; Donato, N.; Saitta, G.; Bonavita, A.; Rizzo, G.; Neri, G.. Sensors Actuat. B-Chem., 2010, 145, 488.
- 14 Pelton, R.. TrAC Trends Anal. Chem., 2009, 28, 925.
- 15 Yu, J.; Wang, S.; Ge, L.; Ge, S.. Biosens. Bioelectron., 2011, 26, 3284.
- 16 Kurra, N.; Kulkarni, G. U.. Lab. Chip., 2013, 13, 2866.
- 17 Carvalhal, R. F.; Kfouri, M. S.; Piazetta, M. H. D.; Gobbi, A. L.; Kubota, L. T.. Anal. Chem., 2010, 82, 1162.
- 18 Zhang, Y.; Wang, G.; Pan, M.. Chem. J. Chin. Univ., 2014, 10, 2234.
- 19 Martinez, A. W.; Phillips, S. T.; Whitesides, G. M.; Carrilho, E.. Anal. Chem., 2010, 82, 3.
- 20 Nie, Z.; Nijhuis, C. A.; Gong, J.; Chen, X.; Kumachev, A.; Martinez, A. W.; Narovlyansky, M.; Whitesides, G. M.. Lab. Chip., 2010, 10, 477.
- 21 Zhao, L. C.; Yan, H. T.. Acta Chim. Sinica, 2012, 70, 1104 (in Chinese).
- 22 Yan, C. F.; Yu, S. Y.; Jiang, Y.; He, Q. H.; Chen, H. G.. Acta Chim. Sinica, 2014, 72, 1099 (in Chinese).
- 23 Nie, Z. H.; Nijhuis, C. A.; Gong, J. L.; Chen, X.; Kumachev, A.; Martinez, A. W.; Narovlyansky, M.; Whitesides, G. M.. Lab. Chip., 2010, 10, 477.
- 24 Liu, W.; Kou, J.; Xing, H.; Li, B.. Biosens. Bioelectron., 2014, 52, 76.
- 25 Hübler, A.; Trnovec, B.; Zillger, T.; Ali, M.; Wetzold, N.; Mingebach, M.; Wagenpfahl, A.; Deibel, C.; Dyakonov, V.. Adv. Eng. Mater., 2011, 1, 1018.
- 26 Fortunato, E.; Correia, N.; Barquinha, P.; Pereira, L.; Goncalves, G.; Martins, R.. IEEE Electron Dev. Lett., 2008, 29, 988.
- 27 Su, A. Q.; Wang, N. F.; Liu, S. Q.; Wu, T.; Peng, S.. Acta Phys.-Chim. Sin., 2012, 28, 1387.
- 28 Yun, S.; Kim, J.. Sensors Actuat. B-Chem., 2010, 150, 308.
- 29 Yang, G.; Lee, C.; Kim, J.; Ren, F.; Pearton, S. J.. Phys. Chem. Chem. Phys., 2013, 15, 1798.
- 30 Wang, Y.; Zang, D.; Ge, S.; Ge, L.; Yu, J.; Yan, M.. Electrochim. Acta, 2013, 107, 147.
- 31 Hossain, S. M.; Brennan, J. D.. Anal. Chem., 2011, 83, 8772.
- 32 Zhang, K.; Zhou, H.; Mei, Q.; Wang, S.; Guan, G.; Liu, R.; Zhang, J.; Zhang, Z.. J. Am. Chem. Soc., 2011, 133, 8424.
- 33 Hossain, S. M. Z.; Luckham, R. E.; McFadden, M. J.; Brennan, J. D.. Anal. Chem., 2009, 81, 9055.
- 34 Kelly, C. A.; Toncelli, C.; Kerry, J. P.; Papkovsky, D. B.. Sensors Actuat. B-Chem., 2014, 203, 935.
- 35 Oikonomou, P.; Botsialas, A.; Olziersky, A.; Goustouridis, D.; Speliotis, A.; Raptis, I.; Sanopoulou, M.. Microelectron. Eng., 2014, 119, 11.
- 36 Razmi, H.; Mohammad-Rezaei, R.. Biosens. Bioelectron., 2013, 41, 498.
- 37 Lu, X.; Zhao, D.; Song, Z.; Wu, B.; Lu, B.; Zhou, X.; Xue, Z.. Biosens. Bioelectron., 2011, 27, 172.
- 38 Chen, J.; Zhou, S.; Wen, J.. Anal. Chem., 2014, 86, 3108.
- 39 Song, C.; Zhi, A.; Liu, Q.; Yang, J.; Jia, G.; Shervin, J.; Tang, L.; Hu, X.; Deng, R.; Xu, C.; Zhang, G.. Biosens. Bioelectron., 2013, 50, 62.
- 40 Zhang, Y.; Wang, Q.; Li, W.; Zhang, J.; Xia, M. H.; Chen, S. M.; Chen, X. M.. Chin. J. Org. Chem., 2014, 34, 403.
- 41 Ye, X. L.; Gu, Y. G.; Wang, C. M.. Sensors Actuat. B-Chem., 2012, 173, 530.
- 42 Ruhling, I.; Schafer, H.; Ternes, W.. Fresen. J. Anal. Chem., 1999, 364, 565.
- 43 Navaratne, A.; Susantha, N.. Anal. Lett., 2000, 33, 1491.
- 44 Morris-Cohen, A. J.; Peterson, M. D.; Frederick, M. T.; Kamm, J. M.; Weiss, E. A.. J. Phys. Chem. Lett., 2012, 3, 2840.
- 45 He, Y.; Yan, X. P.. Sci. China-Chem., 2011, 54, 1254.
- 46 Cordes, D. B.; Gamsey, S.; Singaram, B.. Angew. Chem., Int. Ed., 2006, 45, 3829.
- 47 Matylitsky, V. V.; Dworak, L.; Breus, V. V.; Basche, T.; Wachtveitl, J.. J. Am. Chem. Soc., 2009, 131, 2424.
