Synthesis, Characterizations, Magnetism and Thermal Degradation of a 2-Fold Interpenetrated 3D Cobalt-Organic Framework
Linyan Yang
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorLiangliang Xin
School of Science, Tianjin University, Tianjin 300072, China
Search for more papers by this authorWen Gu
Department of Chemistry, Nankai University, Tianjin 300071, China
Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Tianjin 300071, China
Search for more papers by this authorShengyun Liao
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorPeiyao Du
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorJinlei Tian
Department of Chemistry, Nankai University, Tianjin 300071, China
Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Tianjin 300071, China
Search for more papers by this authorYanping Zhang
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorRui Lv
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorXiaohua Wei
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorCorresponding Author
Xin Liu
Department of Chemistry, Nankai University, Tianjin 300071, China
Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Tianjin 300071, China
Department of Chemistry, Nankai University, Tianjin 300071, China, Tel.: 13512865360; Fax: 0086-022-23502779Search for more papers by this authorDaizheng Liao
Department of Chemistry, Nankai University, Tianjin 300071, China
Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Tianjin 300071, China
Search for more papers by this authorLinyan Yang
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorLiangliang Xin
School of Science, Tianjin University, Tianjin 300072, China
Search for more papers by this authorWen Gu
Department of Chemistry, Nankai University, Tianjin 300071, China
Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Tianjin 300071, China
Search for more papers by this authorShengyun Liao
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorPeiyao Du
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorJinlei Tian
Department of Chemistry, Nankai University, Tianjin 300071, China
Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Tianjin 300071, China
Search for more papers by this authorYanping Zhang
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorRui Lv
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorXiaohua Wei
Department of Chemistry, Nankai University, Tianjin 300071, China
Search for more papers by this authorCorresponding Author
Xin Liu
Department of Chemistry, Nankai University, Tianjin 300071, China
Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Tianjin 300071, China
Department of Chemistry, Nankai University, Tianjin 300071, China, Tel.: 13512865360; Fax: 0086-022-23502779Search for more papers by this authorDaizheng Liao
Department of Chemistry, Nankai University, Tianjin 300071, China
Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Tianjin 300071, China
Search for more papers by this authorAbstract
A new coordination polymer, [Co2(L)2(4,4′-bipy)]n·3nH2O (1) based on 5-(3-methyl-5-phenyl-4H-1,2,4-triazol-4-yl)isophthalic acid (H2L) and 4,4′-bipyridine (4,4′-bipy) has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, XRPD, IR, and elemental analysis. Temperature-dependent magnetic susceptibility and thermal degradation for 1 were also studied. The asymmetric unit of compound 1 consists of two crystallographically independent Co(II) ion, two L2− ligand, one 4,4′-bipy ligand, and three lattice water molecules. The 2D triangle networks were linked by the bridging 4,4′-bipy ligand to give rise to a 2-fold interpenetrated 3D architecture. The simplest cyclic motif of the 2D networks is a triangle ring consisting of three Co(II) cations and three L2− ligands. So we can define Co(II) ions as 4-connected nodes and the L2− ligands as 3-connected nodes. Thus, the 3D structure can be described as a 2-fold parallel interpenetrated ins InS 3,4-conn topology.
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