Synthesis of Enantiopure SunPhos Diphosphine and Its Reaction with Methyl Acrylate
Hong-Wei ZHANG
School of Chemistry and Chemical Technology, Shanghai Jiaotong University, Shanghai 200240, China
Search for more papers by this authorQing-Hua MENG
School of Chemistry and Chemical Technology, Shanghai Jiaotong University, Shanghai 200240, China
Search for more papers by this authorZhao-Guo ZHANG
School of Chemistry and Chemical Technology, Shanghai Jiaotong University, Shanghai 200240, China
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Tel.: 0086-021-54748925; Fax: 0086-021-54748925
Search for more papers by this authorHong-Wei ZHANG
School of Chemistry and Chemical Technology, Shanghai Jiaotong University, Shanghai 200240, China
Search for more papers by this authorQing-Hua MENG
School of Chemistry and Chemical Technology, Shanghai Jiaotong University, Shanghai 200240, China
Search for more papers by this authorZhao-Guo ZHANG
School of Chemistry and Chemical Technology, Shanghai Jiaotong University, Shanghai 200240, China
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Tel.: 0086-021-54748925; Fax: 0086-021-54748925
Search for more papers by this authorGraphical Abstract
Sunphos backbone diphosphine was synthesized from enantiopure diphosphate with the reducing reagents LiAlH4 and Me3SiCl. Sunphos diphosphine reacts with methyl acrylate to give dialkylated electron-rich phosphine.
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