Volume 25, Issue 10 pp. 1581-1583
Full Paper

Synthesis and Characterization of Poly(butylene adipate-co- terephthalate) Catalyzed by Rare Earth Stearates

Kui ZHU

Kui ZHU

Key Laboratory of Macromolecule Synthesis and Functionalization of Ministry of Education, Institute of Polymer Science, Zhejiang University, Hangzhou, Zhejiang 310027, China

Search for more papers by this author
Wei-Pu ZHU

Wei-Pu ZHU

Key Laboratory of Macromolecule Synthesis and Functionalization of Ministry of Education, Institute of Polymer Science, Zhejiang University, Hangzhou, Zhejiang 310027, China

Search for more papers by this author
Yan-Bo GU

Yan-Bo GU

Key Laboratory of Macromolecule Synthesis and Functionalization of Ministry of Education, Institute of Polymer Science, Zhejiang University, Hangzhou, Zhejiang 310027, China

Search for more papers by this author
Zhi-Quan SHEN

Zhi-Quan SHEN

Tel.: 0086-0571-87951059; Fax: 0086-0571-87953727

Search for more papers by this author
Wei CHEN

Wei CHEN

SINOPEC Beijing Research Institute of Chemical Industry, Beijing 100013, China

Search for more papers by this author
Gui-Xiang ZHU

Gui-Xiang ZHU

SINOPEC Beijing Research Institute of Chemical Industry, Beijing 100013, China

Search for more papers by this author
First published: 16 October 2007
Citations: 27

Abstract

Rare earth (Nd, Y, La, Dy) stearates have been synthesized and used as single component catalysts for the polycondensation of dimethyl terephthalate, adipic acid and 1,4-butanediol for the first time preparing biodegradable poly(butylene adipate-co-terephthalate) (PBAT) with high molecular weight. The microstructures of PBAT were characterized by 1H NMR spectra. The PBAT exhibits good mechanical properties such as high tensile strength (ca. 20 MPa) and long break elongation (>700%).

The full text of this article hosted at iucr.org is unavailable due to technical difficulties.