Volume 24, Issue 11 pp. 1669-1673
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Dicyano-Functionalized MCM-41-Supported Palladium Complex as An Efficient Catalyst for Allylation of Aldehydes and Ketones

Hong Zhao

Hong Zhao

Department of Chemistry, Jiangxi Normal University, Nanchang, Jiangxi 330027, China

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Ming-Zhong Cai

Ming-Zhong Cai

Fax: 0086-791-8517500

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First published: 03 November 2006
Citations: 4

Abstract

Dicyano-functionalized MCM-41-supported palladium complex was prepared from dicyano-functionalized MCM-41 and palladium chloride. This complex exhibited high catalytic activity in the allylation of aldehydes and ketones with allylic chlorides in the presence of SnCl2. This polymeric palladium complex can be recovered and reused without noticeable loss of activity.

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