A new sequiterpenoid compound 8aα-hydroxy-1-isopropyl-4,7-dimethyl-1,2,3,4,6,8a-hexahydro-naphthalene-2,6-dione (1), together with seven known compounds anti-HH-dimer-coumarin (2), (−)-5-exo-hydroxy-borneol (3), O-hydroxyl cinnamic acid (4), 9β-hydroxy-ageraphorone (5), 10Hα-9-oxo-ageraphorone (6), 10Hβ-9-oxo-ageraphorone (7) and 9-oxo-10,11-dehydroageraphorone 8, was isolated from the leaves of Eupatorium adenophorum Spreng. The structures were elucidated by IR, ¹H and ¹³C NMR, EIMS, HMBC and single-crystal X-ray spectral data.

REFERENCES

1 Zhu, F. Z.; Yang, G. Z.; Li, G. Q.. Nat. Prod. Res. Dev., 1997, 9, 35 (in Chinese).
CAS Google Scholar
2 Pala-Paul, J.; Perez-Alonso, M. J.; Velasco-Negueruela, A.; Sanz, J.. J. Chromatogr, A, 2002, 947, 327.
10.1016/S0021-9673(02)00016-X
CAS PubMed Web of Science® Google Scholar
3 Fu, Y.; Song, Q.; Fang, Q.. J. Yunnan Agric. Univ., 1999, 14, 411 (in Chinese).
Web of Science® Google Scholar
4 Bohlmann, F.; Gupta, R. K.. Phytochemistry, 1981, 20, 1432.
10.1016/0031-9422(81)80060-X
CAS Web of Science® Google Scholar
5 Sirinart, A.; Kittisak, L.; Nijsiri, R.. J. Org. Chem., 1989, 54, 2253.
10.1021/jo00270a046
Web of Science® Google Scholar
6 Shukla, V. S.; Baura, N. C.; Chaudhury, P. K.; Sharma, R. P.; Bordoloi, M.; Rychlewska, U.. Tetrahedron, 1986, 42, 1157.
10.1016/S0040-4020(01)87521-9
CAS Web of Science® Google Scholar
7 Ding, Z. H.; Ding, J. K.. Chin. Chem. Lett., 1999, 10, 491 (in Chinese).
CAS Web of Science® Google Scholar
8 Xu, Y.-L.; Shan, X.-Z.; Wang, Z.-Y.; Wu, M.. Acta Botanica Yuannanica, 1988, 10, 238 (in Chinese).
CAS Google Scholar
9 Li, R. T.; Ding, Z. H.; Ding, J. K.. Acta Botanica Yuannanica, 1997, 19, 196 (in Chinese).
Web of Science® Google Scholar
10 Ding, Z. H.; Guo, Y. B.; Ding, J. K., Acta Botanica Yuannanica, 1999, 21, 505 (in Chinese).
CAS Web of Science® Google Scholar
11 Gonzalez, G. A.; Diaz, J. G.. Rev. Latinoam. Quim, 1987, 18, 51.
Google Scholar
12 Ansari, S.; Jain, P.. Herba Pol, 1983, 29, 93.
CAS Web of Science® Google Scholar
13 Proksch, P.; Wray, V.; Isman, M. B.; Rahaus, I.. Phytochemistry, 1990, 29, 453.
10.1016/0031-9422(90)85096-X
CAS Web of Science® Google Scholar
14 Zhu, F.-Z.; Yang, G.-Z.; Li, G.-Q.. J. Central China Normal Univ. (Nat. Sci.), 1995, 29, 215 (in Chinese).
Google Scholar
15 Wang, Y. D.; Gao, P.; Zhang, Q. H.. High Technol. Letl., 2002, 12, 21 (in Chinese).
CAS Web of Science® Google Scholar
16 Zhou, T.-X.; Yang, M.-L.; Gu, F.. J. Yunnan Agric. Univ., 2003, 18, 259 (in Chinese).
CAS Web of Science® Google Scholar
17 Baruah, N. C.; Soneswar, J. C.. J. Chem. Ecol., 1994, 20, 1885.
10.1007/BF02066230
CAS PubMed Web of Science® Google Scholar
18 He, A.-J.; Liu, L.-H.. J. Weed Sci., 1990, 4, 35 (in Chinese).
Google Scholar
19 Yu, X. L.; Scheller, D.; Rademacher, O.; Wolff, T.. J. Org. Chem., 2003, 68, 7386.
10.1021/jo034627m
CAS PubMed Web of Science® Google Scholar
20 Gunawardana, Y. A. G. P.; Geoffrey, A. C.. J. Nat. Prod., 1988, 51, 142.
10.1021/np50055a022
CAS Web of Science® Google Scholar
21 Carmichael, J.; Degraff, W. G.; Gazdar, A. F.; Minna, J. D.; Mitchell, J. B.. Cancer Res., 1987, 47, 936.
CAS PubMed Web of Science® Google Scholar
22 Tiew, P.; Takayama, H.; Kitajima, M.; Aimi, N.; Kokpol, U.; Chavasiri, W.. Tetrahedron Lett., 2003, 44, 6759.
10.1016/S0040-4039(03)01616-2
CAS Web of Science® Google Scholar

Citing Literature

Volume24, Issue10

October, 2006

Pages 1375-1377

A new Sequiterpenoid from Eupatorium adenophorum Spreng

Abstract

REFERENCES

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

A new Sequiterpenoid from Eupatorium adenophorum Spreng

Abstract

REFERENCES

Citing Literature

References

Related

Information