Novel Hydrogen-bonded Three-dimensional Supramolecular Architectures Containing 2D Honeycomb Networks or 2D Grids
Dong-Sheng Li
Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi 710069, China
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
Search for more papers by this authorCai-Hua Zhou
Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi 710069, China
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
Search for more papers by this authorFeng Fu
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
Search for more papers by this authorYa-Pan Wu
Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorGuang-Cai Qi
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
Search for more papers by this authorQi-Zhen Shi
Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorDong-Sheng Li
Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi 710069, China
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
Search for more papers by this authorCai-Hua Zhou
Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi 710069, China
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
Search for more papers by this authorFeng Fu
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
Search for more papers by this authorYa-Pan Wu
Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorGuang-Cai Qi
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
Search for more papers by this authorQi-Zhen Shi
Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi 710069, China
Search for more papers by this authorAbstract
Two new supramolecular complexes, [Cu(H2dhbd)(3-pyOH)(H2O)]2·3-pyOH·2H2O (1) and [Cu2(dhbd)(dpa)2- (H2O)]·6H2O (2) (H4dhbd=2,3-dihydroxybutanedioic acid, 3-pyOH=3-hydroxypyridine, dpa=2,2′-dipyridylamine), have been synthesized in aqueous solution and characterized by single-crystal X-ray diffraction, elemental analyses, UV-Vis and IR spectra, and TGA analysis. X-ray structural analysis revealed that, through four pairs of strong O···H–O hydrogen bonds, the cyclic dinuclear units in 1 together with four adjacent neighbors are connected into a 2D honeycomb network encapsulating free 3-pyOH ligands. Unexpectedly, the water-dimers are fixed in interlayers of 2D honeycomb network and act as hydrogen-bond bridging to further extend these 2D networks into 3D hydrogen-bonded framework. Complex 2 includes interesting 2D grids constructed from chiral dinuclear units through strong O···H–O and O···H–N hydrogen bonding, which are extended through other crystallization water molecules into three dimension with channels. Variable-temperature magnetic susceptibility measurements for both complexes indicate the presence of weak antiferromagnetic exchange interactions between adjacent copper(II) ions.
REFERENCES
- 1 Halper, S. R.; Cohen, S. M.. Angew. Chem., Int. Ed., 2004, 43, 2385.
- 2 Sivakova, S.; Bohnsack, D. A.; Mackay, M. E.; Suwanmala, P.; Rowan, S. J.. J. Am. Chem. Soc., 2005, 127, 18202.
- 3 Bond, A. D.; Jones, W., In Supramolecular Organization and Materials Design, Eds.: W. Jones; C. N. R. Rao, Cambridge University Press, Cambridge, 2002.
- 4 Steed, J. W.; Atwood, J. L., Supramolecular Chemistry, Wiley, Chichester, U. K., 2000.
- 5 Du, M.; Zhang, Z. H.; Zhao, X. J.. Cryst. Growth Des., 2005, 5, 1199.
- 6 Zhou, C. H.; Wang, Y. Y.; Zhou, L. J.; Liu, P.; Li, D. S.; Shi, Q. Z.. Chin. J. Chem., 2005, 23, 1371.
- 7 Ranganathan, A.; Chatterjee, S.; Pedireddi, V. R.. Tetrahedron Lett., 1998, 39, 9831.
- 8
Holy, P.;
Zavada, J.;
Cisarova, I.;
Podlaha, J..
Angew. Chem., Int. Ed.,
1999,
38,
381.
10.1002/(SICI)1521-3773(19990201)38:3<381::AID-ANIE381>3.0.CO;2-P CAS Web of Science® Google Scholar
- 9
Aakeröy, C. B.;
Beatty, A. M.;
Helfrich, B. A..
Angew. Chem., Int. Ed.,
2001,
40,
3240.
10.1002/1521-3773(20010903)40:17<3240::AID-ANIE3240>3.0.CO;2-X CAS PubMed Web of Science® Google Scholar
- 10 Fujita, M.; Sasaki, O.; Mitsuhashi, T.; Fujita, T.; Yazaki, Y.; Yamaguchi, K.; Ogura, K.. Chem. Commun., 1996, 1535.
- 11 Rao, C. N. R.; Natarajan, S.; Vaidhyanathan, R.. Angew. Chem., Int. Ed., 2004, 43, 1466.
- 12 Ockwig, N. W.; Delgado-Friedrichs, O.; O'Keeffe, M.; Yaghi, O. M.. Acc. Chem. Res., 2005, 38, 176.
- 13 Wang, Z. W.; Kravtsov, V. C.; Zaworotko, M. J.. Angew. Chem., Int. Ed., 2005, 44, 2877.
- 14 Kitagawa, S.; Kitaura, R.; Noro, S.. Angew. Chem., Int. Ed., 2004, 43, 2334.
- 15a Zheng, S. L.; Yang, J. H.; Yu, X. L.; Chen, X. M.; Wong, W. T.. Inorg. Chem., 2004, 43, 830.
- 15b Zou, R. Q.; Bu, X. H.; Zhang, R. H.. Inorg. Chem., 2004, 43, 5382.
- 15c Wang, X.; Qin, C.; Wang, E.; Li, Y.; Hao, N.; Hu, C.; Xu, L.. Inorg. Chem., 2004, 43, 1850.
- 16 Schwendt, P.; Švanc̆árek, P.; Kuchta, L.; Marek, J.. Polyhedron, 1998, 17, 2161.
- 17 Tapscott, R. E., In Transition Metal Chemistry, Vol. 8, Eds.: G. A. Melson; B. N. Figgis, Marcel Dekker Inc., New York, Basel, 1982, pp. 266–322.
- 18a Li, D. S.; Wang, Y. Y.; Luan, X. J.; Liu, P.; Zhou, C. H.; Ma, H. R.; Shi, Q. Z.. Eur. J. Inorg. Chem., 2005, 2678.
- 18b Li, D. S.; Wang, Y. Y.; Liu, P.; Luan, X. J.; Zhou, C. H.; Shi, Q. Z.. Acta Chim. Sinica, 2005, 63, 1633 (in Chinese).
- 18c Li, D. S.; Wang, Y. Y.; Liu, P.; Zhou, L. J.; Qin, W. L.; Shi, Q. Z.. Acta Chim. Sinica, 2005, 63, 550 (in Chinese).
- 19a Sheldrick, G. M., SHELXS 97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
- 19b Sheldrick, G. M., SHELXL 97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
- 20 Breeze, S. R.; Wang, S. N.. Inorg. Chem., 1993, 32, 5981.
- 21 Malachy, M. C.; Fergal, H.; Vickie, M. K.. Polyhedron, 1997, 16, 3655.
- 22 Du, M.; Guo, Y. M.; Bu, X. H.. Inorg. Chim. Acta, 2003, 346, 207.
- 23
Ludwing, R..
Angew. Chem.,
2001,
40,
1808.
10.1002/1521-3773(20010518)40:10<1808::AID-ANIE1808>3.0.CO;2-1 PubMed Web of Science® Google Scholar
- 24 Bostelaar, L. J.; Graaff, R. A. G.; Hulsbergen, F. B.; Reedijk, J.; Sachtler, W. M. H.. Inorg. Chem., 1984, 23, 2294.
- 25 Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1978, p. 253.
- 26 Carballo, R.; Castineiras, A.; Covelo, B.. Polyhedron, 2001, 20, 899.
- 27 Zhang, L. J.; Xu, J. Q.; Shi, Z.. J. Solid State Chem., 2003, 32, 32.
- 28 Wang, Y. Y.; Wang, X.; Shi, Q. Z.. Trans. Met. Chem., 2002, 27, 481.
- 29 Michael, D.; Mccann, M.; Cronin, J.; Cardin, C.; Todd, A.. Polyhedron, 1996, 15, 785.
- 30 Mccann, M.; Cronin, J.; Devereux, M.; Ferguson, G.. Polyhedron, 1995, 14, 2379.
- 31 Mukhopadhyay, S.; Chatterjee, P. B.; Mandal, D.; Mostafa, G.; Caneschi, A.; Slageren, J. V.; Weakley, T. J. R.; Chaudhury, M.. Inorg. Chem., 2004, 43, 3413.
- 32 Wang, L. Y.; Li, L. C.; Liao, D. Z.; Jiang, Z. H.; Yan, S. P.. Eur. J. Inorg. Chem., 2004, 2266.
- 33 Kahn, O., Molecular Magnetism, VCH Publishers, New York, 1993, pp. 27–107.
- 34 Kato, M.. Coord. Chem. Rev., 1988, 92, 45.
- 35 Mukherjee, P. S.; Ghoshal, D.; Zangrando, E.; Mallah, T.; Chaudhuri, N. R.. Eur. J. Inorg. Chem., 2004, 4675.
- 36 Dalai, S.; Mukherjee, P. S.; Rogez, G.; Mallah, T.; Drew, M. G. B.; Chaudhuri, N. R.. Eur. J. Inorg. Chem., 2002, 3292.
