Catalytic Conversion of 2-Naphthol to 2-Hydroxy-1,4=naphthoquinone Under Mild Conditions
Corresponding Author
Yan Yan
Department of Chemistry, Shantou University, Shantou, Guangdong 515063, China
Fax: 07542902829Search for more papers by this authorHong-Wei Guo
College of Chemistry, Jilin University, Changchun, Jilin 130023, China
Search for more papers by this authorWen-Ping Jian
College of Chemistry, Jilin University, Changchun, Jilin 130023, China
Search for more papers by this authorKe-Er Yang
Department of Chemistry, Shantou University, Shantou, Guangdong 515063, China
Search for more papers by this authorShan-Ling Tong
Department of Chemistry, Shantou University, Shantou, Guangdong 515063, China
Search for more papers by this authorChi-Guang Fang
The Sanitary Detect Center of Jilin Province, Changchun. Jilin 130012. China
Search for more papers by this authorQing Li
The Sanitary Detect Center of Jilin Province, Changchun. Jilin 130012. China
Search for more papers by this authorXin Chang
The Sanitary Detect Center of Jilin Province, Changchun. Jilin 130012. China
Search for more papers by this authorCorresponding Author
Yan Yan
Department of Chemistry, Shantou University, Shantou, Guangdong 515063, China
Fax: 07542902829Search for more papers by this authorHong-Wei Guo
College of Chemistry, Jilin University, Changchun, Jilin 130023, China
Search for more papers by this authorWen-Ping Jian
College of Chemistry, Jilin University, Changchun, Jilin 130023, China
Search for more papers by this authorKe-Er Yang
Department of Chemistry, Shantou University, Shantou, Guangdong 515063, China
Search for more papers by this authorShan-Ling Tong
Department of Chemistry, Shantou University, Shantou, Guangdong 515063, China
Search for more papers by this authorChi-Guang Fang
The Sanitary Detect Center of Jilin Province, Changchun. Jilin 130012. China
Search for more papers by this authorQing Li
The Sanitary Detect Center of Jilin Province, Changchun. Jilin 130012. China
Search for more papers by this authorXin Chang
The Sanitary Detect Center of Jilin Province, Changchun. Jilin 130012. China
Search for more papers by this authorAbstract
2-Hydroxy-1.4-naphthaquinone (HNQ) was selectively synthesized from catalytic oxidation of 2-naphthol by molecular oxygen over tetra(4-methoxyl-phenyl)porphyrinate iron(III) chloride (TMOPPFeCl) catalyst in an alkali methanol solution under mild conditions. The influences of solvents, temperature, time, as well as amounts of catalysts and alkali were studied. The quantitative data show that 32.9% of 2-naphthol (0.093 mol/dm3) was catalytically converted to HNQ with the selectivity of 100% at 323 K for 9 h over TMOPPFeCl catalyst (2.54→10−4 mol/dm3) in alkali media (30 mL of methanol containing 2.5 mol/dm3 of NaOH) by flowing molecular oxygen (flowing rate of 45 mL/min).
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