The study on the factors influencing sulfinatodehalogenation of perfluorohexyl chloride plus octene-1 by using Na₂S₂O₄/NaHCO₃ discovered that among the various solvents tested (e.g. Me₂SO, NMP, DMAc, CH₃CN, CH₃CN/H₂O) at different temperatures, Me₂SO was found to be the most suitable solvent and the conversion of the chloride was very dependent on the reaction temperature. When Me₂SO was used in the reaction of perfluoroalkyl iodides. the reaction temperature could be decreased by 20 °C as compared with that carried out in CH₃CN/H₂O to reach the comparable yields.

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Volume22, Issue4

April 2004

Pages 371-376

Factors Influencing Sulfinatodehalogenation Reactions of Perhalocarbons

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Factors Influencing Sulfinatodehalogenation Reactions of Perhalocarbons

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