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Luminescent Property of a Supramolecular Silver(I)-Thiolate Complex Based on Secondary Ag-S Interactions and Hydrogen Bonds

Wei-Ping Su

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, China

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Mao-Chun Hong,

Mao-Chun Hong

[email protected]

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, China

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Rong Cao,

Rong Cao

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, China

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Jia-Bao Weng,

Jia-Bao Weng

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, China

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Zhong-Yuan Zhou,

Zhong-Yuan Zhou

Open Laboratory of Chirotechnology, Department of Applied Biology and Chemical Technology, the Hong Kong Polytechnic University, Hong Hum, Hong Kong, China

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S. C. Chan Albert,

S. C. Chan Albert

Open Laboratory of Chirotechnology, Department of Applied Biology and Chemical Technology, the Hong Kong Polytechnic University, Hong Hum, Hong Kong, China

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Wei-Ping Su,

Wei-Ping Su

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, China

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Mao-Chun Hong,

Mao-Chun Hong

[email protected]

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, China

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Rong Cao,

Rong Cao

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, China

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Jia-Bao Weng,

Jia-Bao Weng

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, China

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Zhong-Yuan Zhou,

Zhong-Yuan Zhou

Open Laboratory of Chirotechnology, Department of Applied Biology and Chemical Technology, the Hong Kong Polytechnic University, Hong Hum, Hong Kong, China

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S. C. Chan Albert,

S. C. Chan Albert

Open Laboratory of Chirotechnology, Department of Applied Biology and Chemical Technology, the Hong Kong Polytechnic University, Hong Hum, Hong Kong, China

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First published: 26 August 2010

https://doi.org/10.1002/cjoc.20010190902

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Abstract

The supramolecular silver(I)-thiolate complex [Ag(μ₂-SC₄N₂H₄)₂(SCN)]_n has been prepared from the reaction of AgSCN and pyrimidine-2-thiol in DMF. X-ray diffraction analysis shows that the supramolecular structure exhibits one-dimensional chain through the secondary Ag-S interactions and the chains are further linked by strong hydrogen bonds to form a three dimensional network. The luminescence effect from the silver-centered state of S→Ag LMCT in solid state is different from that in solution due to the secondary Ag-S interactions.

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Volume19, Issue9

September 2001

Pages 817-821

Luminescent Property of a Supramolecular Silver(I)-Thiolate Complex Based on Secondary Ag-S Interactions and Hydrogen Bonds

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Luminescent Property of a Supramolecular Silver(I)-Thiolate Complex Based on Secondary Ag-S Interactions and Hydrogen Bonds

Abstract

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