Volume 19, Issue 6 pp. 616-619

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Reductive Cyclodimerization of α, β- Unsaturated Ketones Promoted by AlCl₃/Sm System_: A Facile Synthesis of 2-Aroyl-1,3,4-triaryl Cyclopentanol Derivatives

Xue-Sen Fan,

Xue-Sen Fan

Department of Chemistry, Zhejiang University (Xixi Campus), Hangzhou, Zhejiang 310028, China

College of Chemistry and Environmental Science, Henan Normal University, Xinxiang, Henan 453002, China

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Yong-Min Zhang,

Yong-Min Zhang

[email protected]

Department of Chemistry, Zhejiang University (Xixi Campus), Hangzhou, Zhejiang 310028, China

Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, China

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Xue-Sen Fan,

Xue-Sen Fan

Department of Chemistry, Zhejiang University (Xixi Campus), Hangzhou, Zhejiang 310028, China

College of Chemistry and Environmental Science, Henan Normal University, Xinxiang, Henan 453002, China

Search for more papers by this author

Yong-Min Zhang,

Yong-Min Zhang

[email protected]

Department of Chemistry, Zhejiang University (Xixi Campus), Hangzhou, Zhejiang 310028, China

Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, China

Search for more papers by this author

First published: 26 August 2010

https://doi.org/10.1002/cjoc.20010190614

Citations: 1

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Abstract

Promoted by AlCl₃/Sm bimetallic system, α, β-unsaturated ketones underwent reductive cyclodimerization to afford cyclopentanol derivatives under mild conditions. The reaction is stereocontrolled and regioselective over the competitive carbon-carbon double bond reduction.

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Volume19, Issue6

June 2001

Pages 616-619

Reductive Cyclodimerization of α, β- Unsaturated Ketones Promoted by AlCl₃/Sm System_: A Facile Synthesis of 2-Aroyl-1,3,4-triaryl Cyclopentanol Derivatives

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Reductive Cyclodimerization of α, β- Unsaturated Ketones Promoted by AlCl3/Sm System: A Facile Synthesis of 2-Aroyl-1,3,4-triaryl Cyclopentanol Derivatives

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Reductive Cyclodimerization of α, β- Unsaturated Ketones Promoted by AlCl₃/Sm System_: A Facile Synthesis of 2-Aroyl-1,3,4-triaryl Cyclopentanol Derivatives