Volume 15, Issue 6 pp. 512-527

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Catalytic oxidation of cyclohexene to cyclohexanone by a triple system in acidic aqueous acetonitrile medium

Hua-Ming Li,

Hua-Ming Li

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 190029, China

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Xing-Kai Ye,

Xing-Kai Ye

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 190029, China

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Xiang-Guang Yang,

Xiang-Guang Yang

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 190029, China

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Yue Wu,

Yue Wu

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 190029, China

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Hua-Ming Li,

Hua-Ming Li

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 190029, China

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Xing-Kai Ye,

Xing-Kai Ye

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 190029, China

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Xiang-Guang Yang,

Xiang-Guang Yang

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 190029, China

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Yue Wu,

Yue Wu

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 190029, China

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First published: 27 August 2010

https://doi.org/10.1002/cjoc.19970150605

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Abstract

The catalytic oxidation of cyclohexene to cyclohexanone using Pd(OAc)₂/HQ/FePc wan investigated in an acidic aqueous solution of acetonitrile. The role of each component of this system in the oxidation of cyclohexene was explored by means of UV-VIS, IR., XPS spectroscopy and cyclic voltammetry, respectively. Based on the experimental results, the mechanism of the oxidation of cyclohexene catalysed by Pd(OAc)₂/HQ/FePc was elucidated.

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Volume15, Issue6

November 1997

Pages 512-527

Catalytic oxidation of cyclohexene to cyclohexanone by a triple system in acidic aqueous acetonitrile medium

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Catalytic oxidation of cyclohexene to cyclohexanone by a triple system in acidic aqueous acetonitrile medium

Abstract

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