Syntheses of a new type of chiral phosphines from glucose
Shi Ji-Cheng
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
Search for more papers by this authorWen Ting-Bin
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
Search for more papers by this authorWu Da-Xu
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
Search for more papers by this authorLu Ge-Tan
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
Search for more papers by this authorHong Mao-Chun
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
Search for more papers by this authorLiu Qiu-Tian
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
Search for more papers by this authorKang Bei-Sheng
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
d̊ Present address: Department of Chemistry, Zhongshan University, Guangzhou, Guangdong 510275, China.
Search for more papers by this authorWang Han-Qing
Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China
Search for more papers by this authorLü Shi-Jie
Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China
Search for more papers by this authorShi Ji-Cheng
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
Search for more papers by this authorWen Ting-Bin
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
Search for more papers by this authorWu Da-Xu
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
Search for more papers by this authorLu Ge-Tan
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
Search for more papers by this authorHong Mao-Chun
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
Search for more papers by this authorLiu Qiu-Tian
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
Search for more papers by this authorKang Bei-Sheng
State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 850002, China
d̊ Present address: Department of Chemistry, Zhongshan University, Guangzhou, Guangdong 510275, China.
Search for more papers by this authorWang Han-Qing
Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China
Search for more papers by this authorLü Shi-Jie
Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China
Search for more papers by this authorAbstract
Methyl 3-deoxy-3-(diphenylphosphino)-4,6-O-benzylidene-α-D-altropyranoside (1) and methyl 2-deoxy-2-(diphenylphosphino)-4,6-O-benzylidene-α-D-altropyranoside (2) were prepared from methyl 2,3-anhydro-4,6-O-benzylidene-O-D-mannopyranoside and methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside, respectively, via regioselective and stereospecific ring-opening reactions in high yields. Compounds 1 and 2 were oxidized to give the corresponding phosphine oxides (S and 4).
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