Preparative Inorganic Chemistry
ChemInform Abstract: Oxothiomolybdenum Derivatives of the Superlacunary Crown Heteropolyanion {P8W48}: Structure of [K4{Mo4O4S4 (H2O)3(OH)2}2(WO2) (P8W48O184)]30- and Studies in Solution.
First published: 05 April 2012
Abstract
Reactions of the cyclic lacunary [H7P8W48O184]33- anion with the [Mo2S2O2(H2O)6] 2+ oxothiocation in aqueous medium are investigated by 31P and 183W NMR, and UV/VIS spectroscopy.
