Volume 42, Issue 21
Isocyclic Compounds

ChemInform Abstract: Chemoselective Phosphine-Catalyzed Cascade Annulations Between Two Different Activated Alkenes: Highly Diastereoselective Syntheses of Polysubstituted Cyclohexanes and Cyclopentenes.

Lingchao Cai

Lingchao Cai

State Key Lab. Elem.-Org. Chem., Nankai Univ., Tianjin 300071, Peop. Rep. China

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Bo Zhang

Bo Zhang

State Key Lab. Elem.-Org. Chem., Nankai Univ., Tianjin 300071, Peop. Rep. China

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Guiping Wu

Guiping Wu

State Key Lab. Elem.-Org. Chem., Nankai Univ., Tianjin 300071, Peop. Rep. China

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Haibin Song

Haibin Song

State Key Lab. Elem.-Org. Chem., Nankai Univ., Tianjin 300071, Peop. Rep. China

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Zhengjie He

Zhengjie He

State Key Lab. Elem.-Org. Chem., Nankai Univ., Tianjin 300071, Peop. Rep. China

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First published: 28 April 2011

Abstract

Cascade [2 + 2 + 2] and [2 + 2 + 1] annulations between 2 molecules of 2-arylidene cyanoacetates or malononitriles and 1 molecule of α,β-unsaturated ketones are presented.

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