Volume 42, Issue 21
Preparative Inorganic Chemistry

ChemInform Abstract: Syntheses and Crystal Structures of the closo-Borates M2[B7H7] and M[B7H8] (M: PPh4, PNP, and N(n-Bu4)): The Missing Crystal Structure in the Series [BnHn]2- (n: 6—12).

Florian Schlueter

Florian Schlueter

Fachbereich 9, Anorg. Chem., Bergische Univ.-GH, D-42097 Wuppertal, Germany

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Eduard Bernhardt

Eduard Bernhardt

Fachbereich 9, Anorg. Chem., Bergische Univ.-GH, D-42097 Wuppertal, Germany

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First published: 28 April 2011

Abstract

The first convenient synthesis of the seven-vertex closo-[B7H7]2- anion via O2-oxidation of [B9H9]2- is reported.

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