Organoelement Compounds
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Ruthenium-Catalyzed Hydrosilylation of 1-Alkynes with Novel Regioselectivity.
First published: 18 May 2010
Abstract
For Abstract see ChemInform Abstract in Full Text.
ChemInform Abstract
Predominantly internal adducts are obtained by hydrosilylation of terminal alkynes in the presence of ruthenium catalysts bearing a pentamethylcyclopentadienyl ligand. Minor terminal adducts are formed with high Z-selectivity.
