Volume 33, Issue 44 p. 212
Natural Products
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Efficient Activation of Glycosyl N-(Phenyl)trifluoroacetimidate Donors with Ytterbium(III) Triflate in the Glycosylation Reaction.

Matteo Adinolfi

Matteo Adinolfi

Dip. Chim. Org. Biochim., Univ. Studi “Federico II”, I-80126 Napoli, Italy

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Gaspare Barone

Gaspare Barone

Dip. Chim. Org. Biochim., Univ. Studi “Federico II”, I-80126 Napoli, Italy

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Alfonso Iadonisi

Alfonso Iadonisi

Dip. Chim. Org. Biochim., Univ. Studi “Federico II”, I-80126 Napoli, Italy

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Marialuisa Schiattarella

Marialuisa Schiattarella

Dip. Chim. Org. Biochim., Univ. Studi “Federico II”, I-80126 Napoli, Italy

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First published: 19 May 2010

Abstract

For Abstract see ChemInform Abstract in Full Text.

ChemInform Abstract

Yb(III)-Triflate is reported as a mild, moisture-stable and cheap catalyst for the coupling of trifluoroacetimidates [cf. (I)] with glycosyl acceptors such as (II).

chemical structure image

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