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ChemInform Abstract: Synthesis of Pumiliotoxin C from Molecular Nitrogen as a Nitrogen Source.
First published: 21 May 2010
Abstract
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ChemInform Abstract
The synthesis of the title alkaloid is based on the formation of the quinoline moiety by treatment of keto alkyne (II) with a titanium—nitrogen complex, generated in situ from Ti(O-iPr)4, Li, TmsCl, and nitrogen gas.
