Volume 33, Issue 8
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ChemInform Abstract: Mesotunnels on the Silica Wall of Ordered SBA-15 to Generate Three-Dimensional Large-Pore Mesoporous Networks.

Jie Fan

Jie Fan

Dep. Chem., Fudan Univ., Shanghai 200433, Peop. Rep. China

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Chengzhong Yu

Chengzhong Yu

Dep. Chem., Fudan Univ., Shanghai 200433, Peop. Rep. China

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Limin Wang

Limin Wang

Dep. Chem., Fudan Univ., Shanghai 200433, Peop. Rep. China

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Bo Tu

Bo Tu

Dep. Chem., Fudan Univ., Shanghai 200433, Peop. Rep. China

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Dongyuan Zhao

Dongyuan Zhao

Dep. Chem., Fudan Univ., Shanghai 200433, Peop. Rep. China

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Yasuhiro Sakamoto

Yasuhiro Sakamoto

Dep. Chem., Fudan Univ., Shanghai 200433, Peop. Rep. China

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Osamu Terasaki

Osamu Terasaki

Dep. Chem., Fudan Univ., Shanghai 200433, Peop. Rep. China

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First published: 22 May 2010
Citations: 2

Abstract

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ChemInform Abstract

A modified mesoporous SBA-15 material with interconnecting three-dimensional large-pore network is synthesized by high-temperature hydrothermal treatment in the presence of 1,3,5-trimethylbenzene (autoclave, 403 K, 24 h). The samples are characterized by XRD and HREM. The three-dimensional SBA-15 has many nanosized (2—8 nm) connections/tunnels, which are randomly distributed between one-dimensional channels. Improved pore—pore communication through the mesotunnels on the silica wall in the three-dimensional SBA-15 would facilitate diffusion and transport of molecules between the channels.

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