Volume 33, Issue 8
Heterocyclic Compounds
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ChemInform Abstract: Intramolecular [2 + 2] Photocycloadditions as an Approach Towards the Right-Hand Side of Solanoeclepin A.

Richard H. Blaauw

Richard H. Blaauw

Lab. Org. Chem., Inst. Mol. Stud., Univ. Amsterdam, NL-1018 WS Amsterdam, Neth.

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Jorg C. J. Benningshof

Jorg C. J. Benningshof

Lab. Org. Chem., Inst. Mol. Stud., Univ. Amsterdam, NL-1018 WS Amsterdam, Neth.

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Angeline E. van Ginkel

Angeline E. van Ginkel

Lab. Org. Chem., Inst. Mol. Stud., Univ. Amsterdam, NL-1018 WS Amsterdam, Neth.

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Jan H. van Maarseveen

Jan H. van Maarseveen

Lab. Org. Chem., Inst. Mol. Stud., Univ. Amsterdam, NL-1018 WS Amsterdam, Neth.

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Henk Hiemstra

Henk Hiemstra

Lab. Org. Chem., Inst. Mol. Stud., Univ. Amsterdam, NL-1018 WS Amsterdam, Neth.

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First published: 22 May 2010

Abstract

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ChemInform Abstract

The reaction of the rigid lactone (III) to give (IV) indicates a stereoselective approach of the complex tricyclic core of the title natural substance. The structure of (IV) is determined by X-ray analysis. The synthesis of the starting materials is described.

chemical structure image

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