Volume 32, Issue 45
Natural Products
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ChemInform Abstract: Synthesis of Unsaturated C-Glycosyl Glycines.

Angelika Wernicke

Angelika Wernicke

Lab. Synth. Asymetrique, CNRS, Ec. Sci. Chim. Ind., Univ. Claude Bernard Lyon, F-69622 Villeurbanne, Fr.

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Denis Sinou

Denis Sinou

Lab. Synth. Asymetrique, CNRS, Ec. Sci. Chim. Ind., Univ. Claude Bernard Lyon, F-69622 Villeurbanne, Fr.

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First published: 23 May 2010

Abstract

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ChemInform Abstract

Pd-catalyzed alkylation of 2,3-unsaturated aryl glycoside with N-diphenylmethyleneglycinate (V) followed by acid hydrolysis and saponification provides a facile access to unsaturated C-glycosyl glycines such as (VIII).

chemical structure image

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