Volume 32, Issue 18
Natural Products
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ChemInform Abstract: Oxidation of Natural Targets by Dioxiranes. Part 4. A Novel Approach to the Synthesis of N-Hydroxyamino Acids Using Dioxiranes.

Antonia Detomaso

Antonia Detomaso

Dip. Chim., CNR, Univ. Bari, I-70126 Bari, Italy

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Ruggero Curci

Ruggero Curci

Dip. Chim., CNR, Univ. Bari, I-70126 Bari, Italy

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First published: 27 May 2010

Abstract

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ChemInform Abstract

A high-yielding selective N-hydroxylation of N-Boc protected primary amino acid esters such as (I) and (III) is achieved with methyl(trifluoromethyl)dioxirane under mild conditions.

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