Volume 32, Issue 18
Organoelement Compounds
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ChemInform Abstract: Neighboring Group Participation by Chromium in Substitution Reactions of (η6-Arene)tricarbonylchromium Complexes.

Craig A. Merlic

Craig A. Merlic

Dep. Chem. Biochem., Univ. Calif., Los Angeles, CA 90095, USA

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Michael M. Miller

Michael M. Miller

Dep. Chem. Biochem., Univ. Calif., Los Angeles, CA 90095, USA

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First published: 27 May 2010

Abstract

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ChemInform Abstract

Chromium carbonyl complexes with leaving groups at β- or γ-positions undergo nucleophilic substitution reactions with net retention of stereochemistry by neighboring group participation from the coordinatively saturated chromium atom.

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