ChemInform Abstract: Synthesis of Chiral Molecules Containing Pyridine and 1,3-Pyrimidine Units: Potential Building Blocks for Helicating and Caging Ligands.
Abstract
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ChemInform Abstract
A simple and efficient method for the synthesis of new polydentate ligands containing pyridine and pyrimidine units [cf. (V), (IX)] based on the reaction of appropriate enaminones with optically pure carboxamidine (III) derived from commercially available (-)-myrtenal is described.