ChemInform Abstract: The First Vanadium-Catalyzed Oxidation of Aryl Allylic Selenides with in situ [2,3] Sigmatropic Rearrangement.
Abstract
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ChemInform Abstract
An efficient synthesis of allylic alcohols from a vanadium-catalyzed oxidation of suitably disposed allylic selenides with tandem [2,3] sigmatropic rearrangement is reported.