Volume 32, Issue 7
Preparative Organic Chemistry
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ChemInform Abstract: The First Vanadium-Catalyzed Oxidation of Aryl Allylic Selenides with in situ [2,3] Sigmatropic Rearrangement.

Rich G. Carter

Rich G. Carter

Dep. Chem. Biochem., Univ. Miss., Oxford, MS 38677, USA

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T. Campbell Bourland

T. Campbell Bourland

Dep. Chem. Biochem., Univ. Miss., Oxford, MS 38677, USA

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First published: 30 May 2010

Abstract

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ChemInform Abstract

An efficient synthesis of allylic alcohols from a vanadium-catalyzed oxidation of suitably disposed allylic selenides with tandem [2,3] sigmatropic rearrangement is reported.

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