ChemInform Abstract: 1,4-Asymmetric Reduction of γ-Keto Sulfoxides Bearing the 2,4,6-Triisopropylphenyl Group.
Abstract
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ChemInform Abstract
The reduction of γ-ketosulfoxides bearing the bulky 2,4,6-triisopropylphenyl group with DIBAL affords γ-hydroxy sulfoxides with high stereoselectivity.