Volume 31, Issue 51
Preparative Organic Chemistry
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ChemInform Abstract: 1,4-Asymmetric Reduction of γ-Keto Sulfoxides Bearing the 2,4,6-Triisopropylphenyl Group.

Shuichi Nakamura

Shuichi Nakamura

Dep. Appl. Chem., Nagoya Inst. Technol., Showa, Nagoya 466, Japan

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Masayuki Kuroyanagi

Masayuki Kuroyanagi

Dep. Appl. Chem., Nagoya Inst. Technol., Showa, Nagoya 466, Japan

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Yoshihiko Watanabe

Yoshihiko Watanabe

Dep. Appl. Chem., Nagoya Inst. Technol., Showa, Nagoya 466, Japan

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Takeshi Toru

Takeshi Toru

Dep. Appl. Chem., Nagoya Inst. Technol., Showa, Nagoya 466, Japan

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First published: 31 May 2010

Abstract

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ChemInform Abstract

The reduction of γ-ketosulfoxides bearing the bulky 2,4,6-triisopropylphenyl group with DIBAL affords γ-hydroxy sulfoxides with high stereoselectivity.

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