Physical Inorganic Chemistry
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ChemInform Abstract: The Crystal Structure of the Oxygen-Stabilized η-Phase Zr3V3OxD9.6.
First published: 31 May 2010
Abstract
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ChemInform Abstract
Hydrogen storage capacity and crystal structure of Zr3V3O0.6 and its saturated deuteride Zr3V3OxD9.6 are studied by X-ray and neutron powder diffraction. The structures are refined in space group Fd3m. The results show that the oxygen non-stoichiometry plays a significant role in the two-fold increase of the hydrogen storage capacity of Zr3V3O0.6 compared with the stoichiometric compound Zr3V3O.
