Heterocyclic Compounds
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ChemInform Abstract: Synthesis and Reactivity of 4-Silylated Oxazoles.
First published: 03 June 2010
Abstract
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ChemInform Abstract
Rh-catalyzed decomposition of silylated diazoesters [cf. (I)] and (IX) in the presence of nitriles gives 4-silylated oxazoles. They can be readily converted to derivatives by desilylation, halogenation and Pd-catalyzed cross-coupling.
