Volume 31, Issue 28
Preparative Organic Chemistry
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ChemInform Abstract: Bromoacetone: A New Protective Group for 1,2-Diols Cleavable with Zinc.

S. Chandrasekhar

S. Chandrasekhar

Indian Inst. Chem. Technol., Hyderabad 500 007, India

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Ch. Srinivas

Ch. Srinivas

Indian Inst. Chem. Technol., Hyderabad 500 007, India

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M. Suresh Kumar

M. Suresh Kumar

Indian Inst. Chem. Technol., Hyderabad 500 007, India

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B. Muralidhar

B. Muralidhar

Indian Inst. Chem. Technol., Hyderabad 500 007, India

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First published: 07 June 2010

Abstract

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ChemInform Abstract

Bromoacetone is utilized for the first time as an excellent protective group for 1,2-diols that can be cleaved chemoselectively under neutral conditions viz., refluxing in Zn—MeOH.

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